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Process for generating useful electrophiles from common anions and their application in electrophilic reactions with organic substrates
Process for generating useful electrophiles from common anions and their application in electrophilic reactions with organic substrates
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机译:由普通阴离子产生有用的亲电试剂的方法及其在与有机底物的亲电反应中的应用
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摘要
A process includes substituting a substituent on a substrate. The process includes reacting a salt of an anionic form of the substituent with an electrophilic fluorination agent to provide an electrophile containing a cationic form of the substituent. The electrophile is then electrophilically substituted on the substrate. In some aspects of the process, the substrate can be an aromatic or a non-aromatic. The process can be used for a variety of reactions having electrophilic mechanisms, including halogenation, thiocyanation and nitration.
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