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Addition of Organochromium Reagents to Heteroaryl Aldehydes. Synthesis of Heteroaryl Substituted bis-Allyl Ethers and Homoallyl Ethers

机译：在杂芳基醛中添加有机铬试剂。杂芳基取代的双烯丙基醚和均烯丙基醚的合成

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Heteroaryl substituted allyl and homoallyl alcohols were synthesised with two different method. Synthesis of bis-allyl ethers and homoallyl ethers were carried out via reaction of allyl bromide with allyl alcohols and homoallyl alcohols, respectively. [2.3]-Wittig Rearrangement reactions of heteroaryl substituted bis-allyl ethers were investigated using GC/MS techniques. In these reactions two unexpected products were isolated in high yield.

机译：用两种不同的方法合成杂芳基取代的烯丙基和高烯丙基醇。双烯丙基醚和高烯丙基醚的合成分别通过烯丙基溴与烯丙醇和高烯丙基醇的反应来进行。 [2.3] -Wittig使用GC / MS技术研究了杂芳基取代的双烯丙基醚的重排反应。在这些反应中，以高收率分离出两种意外产物。

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期刊名称 Molecules
作者
S. Servi; C. Topaloglu;
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作者单位

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年(卷),期 2004(9),1
年度 2004
页码 22–28
总页数 7
原文格式 PDF
正文语种
中图分类分子生物学;
关键词
Nozaki-Hiyama reaction Organochromium reagents Hetero-aromatic aldehydes;

机译：野崎Hi山反应;有机铬试剂;杂芳香醛;

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1. Addition of Organochromium Reagents to Heteroaryl Aldehydes. Synthesis of Heteroaryl Substituted bis-Allyl Ethers and Homoallyl Ethers [J] . C. Topaloglu, S. Servi Molecules . 2004,第1期

机译：在杂芳基醛中添加有机铬试剂。杂芳基取代的双烯丙基醚和均烯丙基醚的合成
2. Using heteroaryl-lithium reagents as hydroxycarbonyl anion equivalents in conjugate addition reactions with (S, S)-(+)-pseudoephedrine as chiral auxiliary; Enantioselective synthesis of 3-substituted pyrrolidines [J] . Alonso B., Ocejo M., Carrillo L., The Journal of Organic Chemistry . 2013,第2期

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机译：TI（OPR-I）/ 2介导的分子内核仁酰基取代和分子内羰基加成反应从烯烃中合成1-羟基双环[N.1.0]链烷烃（N = 3和4）和它们的甲硅烷基酯-PRMGCL试剂
4. Synthesis of a New Class of Heteroaryl Dipyrazolyl Carbothioamides and Heteroaryl Dipyrazolyl Thiazoles and Evaluation as Antioxidants [C] . Ummadi Nagarjuna, Gundala Sravya, S. Durgamma, International Conference on Modern Synthetic Methodologies for Creating Drugs and Functional Materials . 2019

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7. Addition of Organochromium Reagents to Heteroaryl Aldehydes. Synthesis of Heteroaryl Substituted bis-Allyl Ethers and Homoallyl Ethers [O] . C. Topaloglu, S. Servi 2004

机译：有机铬试剂添加到杂芳基醛中。杂芳基取代的双烯丙基醚和高烯丙基醚的合成

Addition of Organochromium Reagents to Heteroaryl Aldehydes. Synthesis of Heteroaryl Substituted bis-Allyl Ethers and Homoallyl Ethers

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