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Biaryl Product Formation from Cross-coupling in Palladium-catalyzed Borylation of a Boc Protected Aminobromoquinoline Compound

机译：Boc保护的氨基溴喹啉化合物在钯催化的硼化反应中的交叉偶联形成联芳基产物。

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摘要

The palladium catalyzed borylation of a Boc protected aminobromoquinoline compound with bis(pinacolato)diboron yielded a biaryl compound, resulting from cross coupling, as the major product, instead of the intended boronate, even though no strong base was used. Such results indicate that under certain conditions and with certain substrates, cross coupling can be a major problem during borylation, leading to unintended consequences.

机译：Boc保护的氨基溴喹啉化合物与双（频哪醇）二硼的钯催化硼化反应生成联芳基化合物，尽管没有使用强碱，但由于交叉偶联而不是预期的硼酸酯作为主要产物。这样的结果表明，在某些条件下和某些基质下，交叉耦合可能是硼化过程中的主要问题，从而导致意想不到的后果。

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期刊名称 Molecules
作者
Hao Fang; Jun Yan; Binghe Wang;
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作者单位

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年(卷),期 2004(9),3
年度 2004
页码 178–184
总页数 7
原文格式 PDF
正文语种
中图分类分子生物学;
关键词
Palladium-catalyzed reaction Borylation Cross-coupling;

机译：钯催化反应;硼化;交叉偶联;

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专利

1. Biaryl Product Formation from Cross-coupling in Palladium-catalyzed Borylation of a Boc Protected Aminobromoquinoline Compound [J] . Binghe Wang Molecules . 2004,第3期

机译：Boc保护的氨基溴喹啉化合物在钯催化的硼氢化反应中的交叉偶联形成联芳基产物。
2. Mild and ligand-free palladium-catalyzed cross-couplings between aryl halides and arylboronic acids for the synthesis of biaryls and heterocycle-containing biaryls [J] . Deng CL, Guo SM, Xie YX, European journal of organic chemistry . 2007,第9期

机译：芳基卤化物和芳基硼酸之间温和且无配体的钯催化交叉偶联，用于合成联芳基和含杂环的联芳基
3. Synthesis of biaryls through a one-pot tandem borylation/Suzuki-Miyaura cross-coupling reaction catalyzed by a palladacycle [J] . Wang L., Cui X., Li J., European journal of organic chemistry . 2012,第3期

机译：通过一锅串联的硼化/铃木-宫浦的交叉偶联反应合成paryladacycle联苯芳基
4. Synthesis of N-Boc Protected Hydrazine Diacids as Key Structural Units for the Formation of α-Helix Mimics [C] . Laura Anderson, Melissa Topper, Priyesh Jain American Peptide Symposium . 2009

机译：N-BOC保护的肼二酸的合成作为形成α-Helix模拟的关键结构单元
5. Study towards palladium-catalyzed cross-coupling and zirconium-catalyzed carboalumination and their application to natural product synthesis, such as mycolactones A and B, 2'-O-methylmyxalamides D [D] . Wang, Guangwei 2009

机译：钯催化的交叉偶联和锆催化的碳铝化的研究及其在天然产物合成中的应用，如分枝内酯A和B，2'-O-甲基甲x酰胺D
6. Palladium-catalyzed borylation of aryl (pseudo)halides and its applications in biaryl synthesis [O] . Hong Ji, Jianghong Cai, Nana Gan, 2018

机译：钯催化的芳基（假）卤化物的硼化及其在联芳基合成中的应用
7. Biaryl Product Formation from Cross-coupling in Palladium- catalyzed Borylation of a Boc Protected Aminobromoquinoline Compound [O] . Hao Fang, Jun Yan, Binghe Wang 2015

机译：在钯催化的Boc保护的氨基溴喹啉化合物的硼酸化中交叉偶联的二芳基产物形成

Biaryl Product Formation from Cross-coupling in Palladium-catalyzed Borylation of a Boc Protected Aminobromoquinoline Compound

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