Crystal structure of bis{4-bromo-2-(carbamimidamidoimino)methylphenolato-κ3NN′O}cobalt(III) nitrate dimethylformamide monosolvate

机译：双 {4-溴-2-（咔酰胺酰胺基亚氨基）甲基苯酚基-κ3的晶体结构NNO}硝酸钴（III）二甲基甲酰胺单溶剂化物

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The title compound, [Co(C8H8BrN4O)2]NO3·C3H7NO, is formed of discrete [CoL 2]⁺ cations, nitrate anions and dimethylformamide (DMF) molecules of crystallization. The cation has no crystallographically imposed symmetry. The ligand molecules are deprotonated at the phenol O atom and octahedrally coordinate the Co^III atoms through the azomethine N and phenolate O atoms in a mer configuration. The deprotonated ligand molecules adopt an almost planar conformation. In the crystal lattice, the cations are arranged in layers in the ab plane divided by the nitrate anions and solvent molecules. No π–π stacking is observed. All of the amine H atoms are involved in hydrogen bonding to nitrate, DMF or ligand O atoms or to one of the Br atoms, forming two-dimensional networks parallel to (100).

机译：标题化合物[Co（C8H8BrN4O）2] NO3·C3H7NO由离散的[CoL 2] +阳离子，硝酸根阴离子和二甲基甲酰胺（DMF）结晶分子形成。阳离子没有晶体学对称性。配体分子在苯酚O原子上去质子化，并通过甲亚胺N和苯酚O原子以mer构型八角配位Co ^{III 原子。去质子化的配体分子采用几乎平面的构象。在晶格中，阳离子在ab平面中分层排列，并被硝酸根阴离子和溶剂分子隔开。没有观察到π–π堆积。所有胺H原子都参与与硝酸盐，DMF或配体O原子或Br原子之一键合的氢键，形成与（100）平行的二维网络。}

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期刊名称 Acta Crystallographica Section E: Crystallographic Communications
作者
Elena A. Buvaylo; Katerina A. Kasyanova; Olga Yu. Vassilyeva; Brian W. Skelton;
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作者单位

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年(卷),期 2016(72),Pt 7
年度 2016
页码 907–911
总页数 11
原文格式 PDF
正文语种
中图分类生化遗传学;生化药理学;
关键词
crystal structure monomeric octahedral CosupIII/sup complex Schiff base ligand aminoguanidine 5-bromosalicylaldehyde;

机译：晶体结构;单体八面体Co sup III / sup络合物;席夫碱配体;氨基胍;5-溴水杨基醛;

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专利

1. Crystal structure of bis{4-bromo-2-[(carbamimidamidoimino)methyl]phenolato-κ3N,N′,O}cobalt(III) nitrate dimethylformamide monosolvate [J] . Buvaylo E.A., Kasyanova K.A., Vassilyeva O.Y., Acta Crystallographica Section E: Crystallographic Communications . 2016,第7期

机译：双{4-溴-2-[（氨基甲酰胺基亚氨基）甲基]苯酚基-κ3N，N'，O}硝酸钴（III）二甲基甲酰胺单溶剂化物的晶体结构
2. The crystal structure of bis[(E)-4-bromo-2-({[2-(pyridin-2-yl)ethyl]imino}methyl)phenol]nickel(II) bis[(E)-4-bromo-2-({[2-(pyridin-2-yl)ethyl]imino}methyl)phenolato]nickel(II) bis(perchlorate) methanol monosolvate, a structure containing strong inter-species hydrogen bonds [J] . Okeke U., Otchere R., Gultneh Y., Acta Crystallographica Section E: Crystallographic Communications . 2018,第8期

机译：双[（E）-4-溴-2-（{[2-（吡啶-2-基）乙基]亚氨基}甲基）苯酚]镍（II）双[（E）-4-溴- 2-（{[2-（吡啶-2-基）乙基]亚氨基}甲基）苯酚基]双（高氯酸）镍（II）甲醇单溶剂化物，其结构具有强的种间氢键
3. Crystal structure of dichloridobis{μ-2-methoxy-6-[(methylimino)methyl]phenolato}{2-methoxy-6-[(methylimino)methyl]phenolato}cadmium(II)cobalt(III) monohydrate [J] . Vassilyeva O.Y., Kasyanova K.V., Kokozay V.N., Acta Crystallographica Section E: Crystallographic Communications . 2018,第11期

机译：二氯双双{μ-2-甲氧基-6-[（甲基亚氨基）甲基]苯酚基} {2-甲氧基-6-[（甲基亚氨基）甲基]苯酚基}一水合镉（II）的晶体结构
4. Crystal structure of dichloridobis{μ-2-methoxy-6-(methylimino)methylphenolato}{2-methoxy-6-(methylimino)methylphenolato}cadmium(II)cobalt(III) monohydrate [O] . Olga Yu. Vassilyeva, Katerina V. Kasyanova, Vladimir N. Kokozay, 2018

机译：一水合氯化镉（II）钴（II）的二氯双（二氯）μ（μ-2-甲基氧基-6-（甲基亚氨基）甲基苯酚基）{2-甲基氧基-6-（甲基亚氨基）甲基苯酚基）晶体结构
5. Crystal structure of bis{4-bromo-2-[(carbamimidamidoimino)methyl]phenolato-κ3N,N′,O}cobalt(III) nitrate dimethylformamide monosolvate [O] . Elena A. Buvaylo, Katerina A. Kasyanova, Olga Yu. Vassilyeva, 2016

机译：双{4-溴-2 - [（氨基甲酰亚氨基亚氨基）甲基]苯酚-κ3N，N，O}硝酸钴（III）二甲基甲酰胺单溶剂化物的晶体结构
6. Bis(Di-Isopropylamino) Phosphido and Di-Isopropylaminophosphinidene Metal Carbonyl Complexes from Reactions of Manganese and Cobalt Carbonyls with Bis(Di-Isopropylamino) Phosphine: X-Ray Crystal Structures of (Pr(i2)N)2PMn2 (CO)8H [R] . King, R. B., Fu, W. K., Holt, E. M. 1984

机译：双（二异丙基氨基）亚磷酰基和二异丙基氨基亚膦基金属羰基配合物来自锰和羰基钴与双（二异丙基氨基）膦的反应：（pr（i2）N）2pmn2（CO）8H的X射线晶体结构

Crystal structure of bis­{4-bromo-2-(carb­amim­id­amido­imino)­meth­ylphenolato-κ3NN′O}cobalt(III) nitrate di­methyl­formamide monosolvate

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Crystal structure of bis{4-bromo-2-(carbamimidamidoimino)methylphenolato-κ3NN′O}cobalt(III) nitrate dimethylformamide monosolvate