Synthesis and crystal structure of a two-dimensional CoII coordination polymer: poly(μ3-3-carboxybenzoato)μ2-5-(pyridin-4-yl)-1H2′H-33′-bi124-triazolecobalt(II)

机译：二维CoII配位聚合物：聚（μ3-3-羧基苯并）μ2-5-（吡啶-4-基）-1H2′H-33′-bi 1 24-三唑钴（II）

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In the title compound, [Co(C8H5O4)(C9H6N7)]n, the divalent Co^II atom is six-coordinated to three N atoms from two symmetrical 5-(pyridin-4-yl)-1H,2′H-3,3′-bi[1,2,4-triazole] (H2pyttz) ligands and three O atoms from three symmetrical 3-carboxybenzoate (Hbdic) ligands, leading to a distorted {CoN3O3} octahedral coordination environment. Two Co^II cations are linked by four bridging carboxylate groups to generate a dinuclear [Co2(CO2)4] unit. The dinuclear units are further connected into a chain along [010] via the Hbdic ligands. The other infinite chain, along [100], is formed through the H2pyttz ligands. Finally, the two kinds of chains are cross-linked, by sharing the Co^II cations, into a two-dimensional network. In the crystal, adjacent layers are further linked by O—H⋯N hydrogen bonds into a three-dimensional framework.

机译：在标题化合物[Co（C8H5O4）（C9H6N7）] n中，二价Co ^{II 原子与两个对称的5-（吡啶-4-基）-1H中的三个N原子配位，2'H-3,3'-联[1,2,4-三唑]（H2pyttz）配体和来自三个对称的3-羧基苯甲酸酯（Hbdic）配体的三个O原子，导致扭曲的{CoN3O3}八面体配位环境。两个Co ^{II 阳离子通过四个桥接羧酸根基团连接，生成双核[Co2（CO2）4]单元。双核单元进一步通过Hbdic配体沿着[010]连接成链。沿着[100]的另一条无限链是通过H2pyttz配体形成的。最后，通过共享Co ^{II 阳离子将两种链交联成二维网络。在晶体中，相邻的层通过OHN氢键进一步连接成三维骨架。}}}

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期刊名称 Acta Crystallographica Section E: Crystallographic Communications
作者
Chao-Jun Du; Xiao-Na Zhao; Bao-Yong Chen;
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作者单位

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年(卷),期 2017(73),Pt 11
年度 2017
页码 1779–1781
总页数 9
原文格式 PDF
正文语种
中图分类生化遗传学;生化药理学;
关键词
crystal structure cobalt complex 5-(pyridin-4-yl)-1H2′H-33′-bi(124-triazole) benzene-13-dicarboxylic acid octahedral geometry hydrogen bond;

机译：晶体结构;钴配合物;5-（吡啶-4-基）-1H;2H-33-联（124-三唑）;苯-13-二羧酸;八面体几何;氢键;

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专利

1. Synthesis and crystal structure of a two-dimensional CoII coordination polymer: poly[(μ3-3-carboxybenzoato)[μ2-5-(pyridin-4-yl)-1H,2′H-3,3′-bi[1,2,4-triazole]]cobalt(II)] [J] . Du C.-J., Zhao X.-N., Chen B.-Y. Acta Crystallographica Section E: Crystallographic Communications . 2017,第11期

机译：二维CoII配位聚合物：聚[（μ3-3-羧基苯并）[μ2-5-（吡啶-4-基）-1H，2′H-3,3′-bi [1， 2,4-三唑]]钴（II）]
2. Synthesis, crystal structure and magnetic properties of a two-dimensional cyanide-based heterometallic coordination polymer with cationic piperazinium ligands: poly[aquatetra-μ2-cyanido-κ8C:N-dicyanido-κ2C-(piperazinium-κN4)cobalt(III)copper(II)] [J] . Qin Ying-Lian, Yao Chen-Zhong, Yang Bin-Wu, Acta crystallographica. Section C, Structural chemistry. . 2016,第1期

机译：带有阳离子哌嗪鎓配体的基于氰化物的二维杂金属配位聚合物的合成，晶体结构和磁性II）]
3. Synthesis, crystal structure and magnetic properties of a two-dimensional cyanide-based heterometallic coordination polymer with cationic piperazinium ligands: poly[aquatetra-mu(2)-cyanido-k(8)C:N-dicyanido-k(2)C-(piperazinium-kN(4))cobalt(III)copper(II)] [J] . Qin Ying-Lian, Yao Chen-Zhong, Yang Bin-Wu, Acta crystallographica. Section F, Structural biology communications . 2016,第1期

机译：用阳离子哌嗪配体的二维氰化物的杂象配位聚合物的合成，晶体结构和磁性性质：Poly [Aquattra-mu（2） - 氰基-K（8）C：N-二氰基-K（2）C- （Piperazinium-KN（4））钴（III）铜（II）]
4. Construction of one new coordination polymers based on 5-(pyridin-4-yl)isophthalic acid acid ligands: synthesis, crystal structures and magnetism [C] . Ya-Ning Wang, Shi-Jie Li, Wen-Dong Song International Conference on Mechatronics, Robotics and Automation . 2015

机译：基于5-（吡啶-4-基）间苯二甲酸配体的一种新配位聚合物的构建：合成，晶体结构和磁
5. Part I. Synthesis of liquid crystalline polymers and coatings. Part II. Structure/property relationships of oligoester diols of low PDI [D] . Kangas, Steven Lee 1988

机译：第一部分：液晶聚合物和涂层的合成。第二部分低PDI的低聚酯二醇的结构/性质关系
6. Crystal structure of a CoII coordination polymer: catena-polyμ-aqua-bis(μ-2-methylpropanoato)-κ2O:O′;κ2O:O-cobalt(II) monohydrate [O] . Andrei I. Fischer, Vladislav V. Gurzhiy, Julia V. Aleksandrova, 2017

机译：CoII配位聚合物的晶体结构：链状聚μ-水-双（μ-2-甲基丙）-κ2O：O′;κ2O：O-钴（II）一水合物
7. Synthesis and crystal structure of a two-dimensional CoII coordination polymer: poly[(μ3-3-carboxybenzoato)[μ2-5-(pyridin-4-yl)-1H,2′H-3,3′-bi[1,2,4-triazole]]cobalt(II)] [O] . Chao-Jun Du, Xiao-Na Zhao, Bao-Yong Chen 2017

机译：二维CoII配位聚合物的合成和晶体结构：聚[（μ3-3-羧基苯甲酸酯）[μ2-5-（吡啶-4-基）-1H，2'H-3,3'-bi [1， 2,4-三唑]]钴（II）]

Synthesis and crystal structure of a two-dimensional CoII coordination polymer: poly(μ3-3-carb­oxy­benzoato)μ2-5-(pyridin-4-yl)-1H2′H-33′-bi124-triazolecobalt(II)

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Synthesis and crystal structure of a two-dimensional CoII coordination polymer: poly(μ3-3-carboxybenzoato)μ2-5-(pyridin-4-yl)-1H2′H-33′-bi124-triazolecobalt(II)