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PNAS Plus: Dynamics of frequency-swept nuclear spin optical pumping in powdered diamond at low magnetic fields

机译:PNAS Plus:低磁场下粉状金刚石中扫频核自旋光学泵浦的动力学

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摘要

A broad effort is underway to improve the sensitivity of NMR through the use of dynamic nuclear polarization. Nitrogen vacancy (NV) centers in diamond offer an appealing platform because these paramagnetic defects can be optically polarized efficiently at room temperature. However, work thus far has been mainly limited to single crystals, because most polarization transfer protocols are sensitive to misalignment between the NV and magnetic field axes. Here we study the spin dynamics of NV−13C pairs in the simultaneous presence of optical excitation and microwave frequency sweeps at low magnetic fields. We show that a subtle interplay between illumination intensity, frequency sweep rate, and hyperfine coupling strength leads to efficient, sweep-direction-dependent 13C spin polarization over a broad range of orientations of the magnetic field. In particular, our results strongly suggest that finely tuned, moderately coupled nuclear spins are key to the hyperpolarization process, which makes this mechanism distinct from other known dynamic polarization channels. These findings pave the route to applications where powders are intrinsically advantageous, including the hyperpolarization of target fluids in contact with the diamond surface or the use of hyperpolarized particles as contrast agents for in vivo imaging.
机译:目前正在进行广泛的努力,以通过使用动态核极化来提高NMR的灵敏度。钻石中的氮空位(NV)中心提供了一个吸引人的平台,因为这些顺磁缺陷可以在室温下有效地被光学极化。但是,迄今为止的工作主要限于单晶,因为大多数极化传输协议对NV和磁场轴之间的未对准很敏感。在这里,我们研究了在低磁场下同时存在光激发和微波频率扫描的NV− 13 C对的自旋动力学。我们表明,照明强度,扫频率和超精细耦合强度之间的微妙相互作用导致了在广泛的磁场方向范围内有效的,依赖于扫频方向的 13 C自旋极化。特别是,我们的结果强烈表明,微调,适度耦合的核自旋是超极化过程的关键,这使该机制与其他已知的动态极化通道不同。这些发现为粉末在本质上是有利的应用铺平了道路,包括与钻石表面接触的目标流体超极化或将超极化颗粒用作体内成像的造影剂。

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