Crystal structures of the potassium and rubidium salts of (35-dichlorophenoxy)acetic acid: two isotypic coordination polymers

机译：（35-二氯氯苯氧基）乙酸的钾盐和rub盐的晶体结构：两种同型配位聚合物

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The two-dimensional coordination polymeric structures of the hydrated potassium and rubidium salts of (3,5-dichlorophenoxy)acetic acid (3,5-D), namely, poly[μ-aqua-bis[μ3-2-(3,5-dichlorophenoxy)acetato]dipotassium], [K2(C8H5Cl2O3)2(H2O)]n, and poly[μ-aqua-bis[μ3-2-(3,5-dichlorophenoxy)acetato]dirubidium], [Rb2(C8H5Cl2O3)2(H₂O)]_n, respectively, have been determined and are described. The two compounds are isotypic and the polymeric structure is based on centrosymmetric dinuclear bridged complex units. The irregular six-coordination about the alkali cations comprises a bridging water molecule lying on a twofold rotation axis, the phenoxy O-atom donor and a triple bridging carboxylate O atom of the oxoacetate side chain of the 3,5-D ligand, and the second carboxyate O-atom donor also bridging. The K—O and Rb—O bond-length ranges are 2.7238 (15)–2.9459 (14) and 2.832 (2)–3.050 (2) Å, respectively, and the K⋯K and Rb⋯Rb separations in the dinuclear units are 4.0214 (7) and 4.1289 (6) Å, respectively. Within the layers which lie parallel to (100), the coordinating water molecule forms an O—H⋯O hydrogen bond to the single bridging carboxylate O atom.

机译：（3,5-二氯苯氧基）乙酸（3,5-D）的水合钾盐和rub盐的二维配位聚合物结构，即聚[μ-aqua-bis[μ3-2-（3,5） -[dichlorophenoxy）acetato] dipotassium]，[K2（C8H5Cl2O3）2（H2O）] n和聚[μ-aqua-bis[μ3-2-（3,5-dichlorophenoxy）acetato] dirubidium]，[Rb2（C8H5Cl2O3）已经确定并描述了2（H _{2 O）] _{n 。这两种化合物是同型的，并且聚合物结构基于中心对称的双核桥联复杂单元。关于碱金属阳离子的不规则六配位包括位于两倍旋转轴上的桥联水分子，3,5-D配体氧代乙酸酯侧链的苯氧基O原子供体和三桥联羧酸根O原子，以及第二个羧酸盐O原子供体也桥接。 K-O和Rb-O键长范围分别为2.7238（15）–2.9459（14）和2.832（2）–3.050（2）Å，双核单元中的K⋯K和Rb⋯Rb间距分别为4.0214（7）和4.1289（6）Å。在平行于（100）的层中，配位水分子与单个桥连羧酸O原子形成OH-H = O氢键。}}

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期刊名称 Acta Crystallographica Section E: Crystallographic Communications
作者
Graham Smith;
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作者单位

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年(卷),期 2015(71),Pt 10
年度 2015
页码 1177–1180
总页数 12
原文格式 PDF
正文语种
中图分类生化遗传学;生化药理学;
关键词
crystal structure coordination polymers (35-dichlorophenoxy)acetic acid 35-D potassium and rubidium salts hydrogen bonding;

机译：晶体结构;配位聚合物;（35-二氯氯苯氧基）乙酸;35-D;钾盐和rub盐;氢键;

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1. Crystal structures of the potassium and rubidium salts of (3,5-dichlorophenoxy)acetic acid: two isotypic coordination polymers [J] . Smith G. Acta Crystallographica Section E: Crystallographic Communications . 2015,第10期

机译：（3,5-二氯苯氧基）乙酸的钾盐和rub盐的晶体结构：两种同型配位聚合物
2. Crystal structures of the potassium and rubidium salts of (3,5-dichlorophenoxy)acetic acid: two isotypic coordination polymers [J] . Smith G. Acta Crystallographica Section E: Crystallographic Communications . 2015,第10期

机译：（3,5-二氯苯氧基）乙酸的钾盐和rub盐的晶体结构：两种同型配位聚合物
3. Two-dimensional hydrogen-bonded polymers in the crystal structures of the ammonium salts of phenoxyacetic acid, (4-fluorophenoxy)acetic acid and (4-chloro-2-methylphenoxy)acetic acid [J] . Smith G. Acta Crystallographica Section E: Crystallographic Communications . 2014,第12期

机译：苯氧基乙酸，（4-氟苯氧基）乙酸和（4-氯-2-甲基苯氧基）乙酸铵盐的晶体结构中的二维氢键聚合物
4. Construction of one new coordination polymers based on 5-(pyridin-4-yl)isophthalic acid acid ligands: synthesis, crystal structures and magnetism [C] . Ya-Ning Wang, Shi-Jie Li, Wen-Dong Song International Conference on Mechatronics, Robotics and Automation . 2015

机译：基于5-（吡啶-4-基）间苯二甲酸配体的一种新配位聚合物的构建：合成，晶体结构和磁
5. Metal coordination polymers and organic co-crystals of polybenzoic acids and bipyridines. [D] . Lo, Man Fung. 2000

机译：金属配位聚合物和聚苯甲酸和联吡啶的有机共晶体。
6. Crystal structures and hydrogen bonding in the anhydrous tryptaminium salts of the isomeric (24-dichlorophenoxy)acetic and (35-dichlorophenoxy)acetic acids [O] . Graham Smith, Daniel E. Lynch 2015

机译：（24-二氯氯苯氧基）乙酸和（35-二氯氯苯氧基）乙酸异构体的无水色胺盐的晶体结构和氢键
7. Crystal structures of the potassium and rubidium salts of (3,5-dichlorophenoxy)acetic acid: two isotypic coordination polymers [O] . Graham Smith 2015

机译：（3,5-二氯苯氧基）乙酸的钾盐和铷盐的晶体结构：两种同型配位聚合物
8. Information Concerning a Manufacturing Impurity with Acetic Acid, ((5-chloro-8-quinolinyl)oxy)-, 1-Methyhexyl Ester(Cloquintocet-Mexyl) and Heptan-2-yl((5- ((5-chloroquinolin- 8-yl)oxy)quinolin-8-yl) oxy)acetate. [R] . 2012

机译：关于制造杂质的信息，用乙酸，（（5-氯-8-喹啉基）氧基） - ，1-甲基己基酯（Cloquintocet-mexyl）和庚-2-基（（5-（（5-氯喹啉-8-）（氧）喹啉-8-基）氧基）乙酸酯。

Crystal structures of the potassium and rubidium salts of (35-di­chloro­phen­oxy)acetic acid: two isotypic coordination polymers

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Crystal structures of the potassium and rubidium salts of (35-dichlorophenoxy)acetic acid: two isotypic coordination polymers