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Synthesis and Characterization of bis(2-ethyl-5-methyl-imidazo-4-yl)methylSulfide and Its Coordination Behavior toward Cu(II) as a Possible Approach of a Copper Site Type I

机译：双（2-乙基-5-甲基-咪唑-4-基）甲基硫化物的合成表征及其与Cu（II）的配位行为作为一种I型铜位点的可能方法

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摘要

The synthesis and characterization of a novel ligand, bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]sulfide (bemims), as well as a bemims-containing copper(II) coordination complex are described. In this complex, [Cu(bemims)X 2] with X = NO3 ⁻, bemims acts as a tridentate ligand and two monodentate nitrate ions complete the coordination sphere. Both imidazole N atoms and the thioether S atom of bemims participate in coordination. The Cu(II) ion is five-coordinated with a slightly distorted square-pyramidal geometry (τ = .09). Electrochemical studies and spectroscopic data for this complex are compared with some blue copper proteins in order to assess its ability to mimic the copper center of type I copper proteins.

机译：描述了新型配体双[（（2-乙基-5-甲基-咪唑基-4-基）甲基]硫化物（半成品）以及含半成品的铜（II）配合物的合成与表征。在这种络合物中，[Cu（bemims）X 2]的X = NO3 ^{-，bemims充当三齿配体，两个单齿硝酸根离子完成配位球。贝米的咪唑N原子和硫醚S原子均参与配位。 Cu（II）离子是五配位的，具有稍微扭曲的方锥几何形状（τ= .09）。将该复合物的电化学研究和光谱数据与某些蓝色铜蛋白进行了比较，以评估其模拟I型铜蛋白的铜中心的能力。}

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期刊名称 Bioinorganic Chemistry and Applications
作者
Juan D. Barrón-Garcés; Guillermo Mendoza-Díaz; Florina Vilchez-Aguado; Sylvain Bernès;
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年(卷),期 2009(2009),-1
年度 2009
页码 905320
总页数 5
原文格式 PDF
正文语种
中图分类分子生物学;
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1. Synthesis and Characterization of bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]Sulfide and Its Coordination Behavior toward Cu(II) as a Possible Approach of a Copper Site Type I [J] . Juan D.Barrón-Garcés, GuillermoMendoza-Díaz, FlorinaVilchez-Aguado, Bioinorganic chemistry and applications . 2009,第7期

机译：双[（2-乙基-5-甲基-咪唑-4-基）甲基]硫化物的合成，表征及其与Cu（II）的配位行为可能是I型铜位点的可能途径
2. Coordination behavior of 3,4-bis(2-pyridylmethylthio)toluene with copper(II) ions: Synthesis, structural characterization and reactivity, and DNA binding study of the dinuclear copper(II) complex [J] . Sarkar S., Sen S., Dey S., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2010,第17期

机译：3,4-双（2-吡啶基甲硫基）甲苯与铜（II）离子的配位行为：双核铜（II）配合物的合成，结构表征和反应活性以及DNA结合研究
3. A novel three-dimensional network constructed from tetramolybdate clusters linked via two types of copper complex fragments: Synthesis, characterization, and magnetic behavior of [{Cu-II(2,2 '-bpy)}{Cu-II(IN)(2)}{Mo4O12(OH)(2)}] [J] . Lu J., Shen EH., Yuan M., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2003,第22期

机译：由四钼酸盐簇通过两种类型的铜络合物片段连接构成的新型三维网络：[{Cu-II（2,2'-bpy）} {Cu-II（IN）（2）的合成，表征和磁行为）} {Mo4O12（OH）（2）}]
4. Synthesis and Crystal Structure of a New Copper(II) Coordination Polymer Cu(II)C_(16) H_(18) N_4O_4S_n [C] . LI Jia-gui, ZHU Wan-ren, DING Shu-hong, International Conference on Chemical Engineering and Advanced Materials . 2012

机译：新型铜（II）配位聚合物的合成和晶体结构Cu（II）C_（16）H_（18）N_4O_4S _N
5. Immobilized bis -phenanthroline coordination sites in porous silica: Characterization and reactivity of manganese(II) and iron(II) complexes [D] . Terry, Tracy J. 2007

机译：多孔二氧化硅中固定的双邻菲咯啉配位点：锰（II）和铁（II）配合物的表征和反应活性
6. Electrochemical Synthesis and Structural Characterization of a Novel Mixed-valence Copper (I)-copper (II) Complex: {Bis(ethylenediamine) Copper (II) Bisdiiodocuprate (I)} [O] . Lida Fotouhi, Saeed Dehghanpour, Majid M. Heravi, 2007

机译：新型混合价铜（I）-铜（II）配合物的电化学合成和结构表征：{双（乙二胺）铜（II）双二碘多丁酸酯（I）}
7. Synthesis and Characterization of bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]Sulfide and Its Coordination Behavior toward Cu(II) as a Possible Approach of a Copper Site Type I [O] . Barrón-Garcés, Juan D., Mendoza-Díaz, Guillermo, Vilchez-Aguado, Florina, 2009

机译：双[（2-乙基-5-甲基-咪唑-4-基）甲基]硫化物的合成，表征及其与Cu（II）的配位行为作为一种I型铜位点的可能方法

Synthesis and Characterization of bis(2-ethyl-5-methyl-imidazo-4-yl)methylSulfide and Its Coordination Behavior toward Cu(II) as a Possible Approach of a Copper Site Type I

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