Synthesis and Characterization of Privileged Monodentate Phosphoramidite Ligands and Chiral Brønsted Acids Derived from d-Mannitol

机译：特权单齿亚磷酰胺配体和d-甘露糖醇衍生的手性布朗斯台德酸的合成与表征

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The synthesis of several novel chiral phosphoramidite ligands (>L1–>L8) with C2 symmetric, pseudo C2 symmetric secondary amines and chiral Brønsted acids >1a,b has been achieved. These chiral auxiliaries were obtained from commercially available d-mannitol, and secondary amines in moderate to excellent yields. Excellent diastereoselectivites of ten chiral auxiliaries were obtained. The chiral phosphoramidite ligands and chiral Brønsted acids were fully characterized by spectroscopic methods.

机译：几种新颖的手性亚磷酰胺配体（> L1 – > L8 ）与C2对称，伪C2对称仲胺和手性布朗斯台德酸> 1a，b 的合成已经实现。这些手性助剂从市售的d-甘露糖醇和仲胺以中等至极好的收率获得。获得了十种手性助剂的优异的非对映选择性。手性亚磷酰胺配体和手性布朗斯台德酸通过光谱方法得到了充分表征。

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期刊名称 International Journal of Molecular Sciences
作者
Abdullah Mohammed A. Al-Majid; Assem Barakat; Yahia Nasser Mabkhot; Mohammad Shahidul Islam;
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作者单位

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年(卷),期 2012(13),3
年度 2012
页码 2727–2743
总页数 17
原文格式 PDF
正文语种
中图分类分子生物学;
关键词
phosphoramidite Brønsted acid d-mannitol;

机译：亚磷酰胺;布朗斯台德酸;d-甘露醇;

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专利

1. Synthesis and Characterization of Privileged Monodentate Phosphoramidite Ligands and Chiral Brønsted Acids Derived from d-Mannitol [J] . Abdullah Mohammed A. Al-Majid, Assem Barakat, Mohammad Shahidul Islam, International Journal of Molecular Sciences . 2012,第3期

机译：特权单齿亚磷酰胺配体和d-甘露糖醇衍生的手性布朗斯台德酸的合成与表征
2. Synthesis of Chiral,Monodentate Aminophosphane and Phosphoramidite Ligands Derived from Amino Acid Esters:Application in Rh-Catalysed Asymmetric Olefin Hydrogenation Reactions [J] . Luc Eberhardt, Dominique Armspach, Dominique Matt European journal of inorganic chemistry . 2007,第26期

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3. Synthesis and structural characterization of a new class of strong chiral Br?nsted acids: 1,1′-binaphthyl-2,2′-bis(sulfuryl)imides (JINGLEs) [J] . Berkessel A., Christ P., Leconte N., European journal of organic chemistry . 2010,第27期

机译：新型强手性布朗斯台德酸的合成与结构表征：1,1'-联萘-2,2'-双（磺酰基）酰亚胺（JINGLEs）
4. Asymmetric Hetero-Diels–Alder Reaction of Non-activated Substrates Utilizing Dual Activation of Cationic Fe(III) Lewis Acid and Chiral Br?nsted Acid [C] . Rei Tomifuji, Takuya Kurahashi, Seijiro Matsubara 日本化学会春季年会講演予稿集 . 2018

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5. Part I. Hz166, a novel γ-aminobutyric acid (A) receptor subtype-selective ligand active against neuropathic pain Part II. The first enantiospecific, stereospecific total synthesis of the C-19 methyl substituted sarpagine indole alkaloids 19(S), 20(R), 19-(S),20(R)dihydroperaksine-17-al and peraksine Part III. Application of metal-carbenoid chemistry and Brönsted acid mediated cyclization of enaminones for the rapid and efficient access to the tetracyclic (ABCE) skeleton of the Strychnos alkaloids contained in bisindole alkaloids [D] . Edwankar, Rahul V. 2010

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6. Synthesis and Characterization of Some New C2 Symmetric Chiral Bisamide Ligands Derived from Chiral Feist’s Acid [O] . Abdullah M. A. Al Majid, Mohammad Shahidul Islam, Zeid Abdullah Al-Othman, 2012

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7. Synthesis and Characterization of Privileged Monodentate Phosphoramidite Ligands and Chiral Brønsted Acids Derived from D-Mannitol [O] . Mohammad Shahidul Islam, Assem Barakat, Abdullah Mohammed A. Al-Majid, 2012

机译：D-甘露糖醇衍生的特权单齿亚磷酰胺配体和手性布朗斯台德酸的合成与表征

Synthesis and Characterization of Privileged Monodentate Phosphoramidite Ligands and Chiral Brønsted Acids Derived from d-Mannitol

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