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Protein self-assembly onto nanodots leads to formation of conductive bio-based hybrids

机译:蛋白质自组装到纳米点上导致形成导电的基于生物的杂种

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摘要

The next generation of nanowires that could advance the integration of functional nanosystems into synthetic applications from photocatalysis to optical devices need to demonstrate increased ability to promote electron transfer at their interfaces while ensuring optimum quantum confinement. Herein we used the biological recognition and the self-assembly properties of tubulin, a protein involved in building the filaments of cellular microtubules, to create stable, free standing and conductive sulfur-doped carbon nanodots-based conductive bio-hybrids. The physical and chemical properties (e.g., composition, morphology, diameter etc.) of such user-synthesized hybrids were investigated using atomic and spectroscopic techniques, while the electron transfer rate was estimated using peak currents formed during voltammetry scanning. Our results demonstrate the ability to create individually hybrid nanowires capable to reduce energy losses; such hybrids could possibly be used in the future for the advancement and implementation into nanometer-scale functional devices.
机译:下一代纳米线可能将功能纳米系统集成到从光催化到光学器件的合成应用中,这需要证明其在确保最佳量子限制的同时具有增强的促进电子在其界面处转移的能力。本文中,我们利用微管蛋白(一种与构建细胞微管细丝有关的蛋白质)的生物识别和自组装特性,来创建稳定,自立和导电的掺硫碳纳米点基导电生物杂交体。使用原子和光谱技术研究了此类用户合成的杂化剂的物理和化学性质(例如,组成,形态,直径等),而使用伏安法扫描过程中形成的峰值电流估算了电子传输速率。我们的结果证明了创建能够降低能量损失的单独混合纳米线的能力。这样的混合体将来可能会用于纳米级功能器件的发展和实现。

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