首页> 美国卫生研究院文献>ACS Omega >Synthesis of Ethylene Glycol from Syngas via OxidativeDouble Carbonylation of Ethanol to Diethyl Oxalate and Its SubsequentHydrogenation

【2h】

Synthesis of Ethylene Glycol from Syngas via OxidativeDouble Carbonylation of Ethanol to Diethyl Oxalate and Its SubsequentHydrogenation

机译：合成气氧化法合成乙二醇乙醇双羰基化为草酸二乙酯及其后续产物氢化

代理获取

本网站仅为用户提供外文OA文献查询和代理获取服务，本网站没有原文。下单后我们将采用程序或人工为您竭诚获取高质量的原文，但由于OA文献来源多样且变更频繁，仍可能出现获取不到、文献不完整或与标题不符等情况，如果获取不到我们将提供退款服务。请知悉。

页面导航

摘要
著录项
相似文献
相关主题

摘要

This work reports a novel sustainable two-step method for the synthesis of ethylene glycol (EG) using syngas. In the first step, diethyl oxalate was selectively synthesized via oxidative double carbonylation of ethanol and carbon monoxide (CO) using a ligand-free, recyclable Pd/C catalyst. In the second step, the diethyl oxalate produced underwent subsequent hydrogenation using [2-(di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride to get EG and ethanol. Thus, the generated ethanol can be recycled back to the first step for double carbonylation. This method gives a sustainable route to manufacture EG using carbon monoxide and hydrogen.

机译：这项工作报告了使用合成气合成乙二醇（EG）的新型可持续两步法。第一步，使用无配体的可循环Pd / C催化剂，通过乙醇和一氧化碳（CO）的氧化双羰基化选择性地合成草酸二乙酯。在第二步中，随后使用[2-（二叔丁基膦基甲基）-6-（二乙基氨基甲基）吡啶]钌（II）氯羰基氢化物氢化生成的草酸二乙酯，进行氢化，得到EG和乙醇。因此，产生的乙醇可以再循环回到第一步以进行双羰基化。该方法为使用一氧化碳和氢气生产EG提供了可持续的途径。

著录项

期刊名称 ACS Omega
作者
Anilkumar Satapathy; Sandip T. Gadge; Bhalchandra M. Bhanage; *;
展开▼
作者单位

展开▼
年(卷),期 2018(3),9
年度 2018
页码 11097–11103
总页数 7
原文格式 PDF
正文语种
中图分类
关键词

相似文献

外文文献
中文文献
专利

1. Synthesis of Ethylene Glycol from Syngas via Oxidative DoubleCarbonylation of Ethanol to Diethyl Oxalate and Its SubsequentHydrogenation [J] . Anilkumar Satapathy, Sandip T. Gadge, Bhalchandra M. Bhanage ACS Omega . 2018,第9期

机译：乙醇的氧化双羰基化合成草酸二乙酯由合成气合成乙二醇及其加氢反应
2. Highly selective synthesis of ethylene glycol and ethanol via hydrogenation of dimethyl oxalate on Cu catalysts: Influence of support [J] . Yifeng Zhu, Yulei Zhu, Guoqiang Ding Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2013,第Null期

机译：铜催化剂上草酸二甲酯加氢高选择性合成乙二醇和乙醇的影响：载体的影响
3. Highly selective synthesis of ethylene glycol and ethanol via hydrogenation of dimethyl oxalate on Cu catalysts: Influence of support [J] . Yifeng Zhu, Yulei Zhu, Guoqiang Ding Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2013,第Null期

机译：铜催化剂上草酸二甲酯加氢高选择性合成乙二醇和乙醇的影响：载体的影响
4. Ethylene glycol and ethanol synthesis from dimethyl oxalate hydrogenation on the Cu/ZnO/SiO2 catalysts [C] . Li Xinbao, Wang Shurong, Zhu Lingjun, 2011 World Congress on Sustainable Technologies . 2011

机译：草酸二甲酯在Cu / ZnO / SiO 2 催化剂上加氢合成乙二醇和乙醇
5. Novel routes to ethylene glycol synthesis via acid-catalyzed carbonylation of formaldehyde and dimethoxymethane. [D] . Celik, Fuat Emin. 2010

机译：通过酸催化甲醛和二甲氧基甲烷羰基化合成乙二醇的新途径。
6. Synthesis and Characterization of Star Poly(ε-caprolactone)-b-Poly(ethylene glycol) and Poly(l-lactide)-b-Poly(ethylene glycol) Copolymers: Evaluation as Drug Delivery Carriers [O] . Fei Wang, Tatiana K. Bronich, Alexander V. Kabanov, -1

机译：星形聚（ε-己内酯）-b-聚（乙二醇）和聚（l-丙交酯）-b-聚（乙二醇）共聚物的合成和表征：评价作为药物输送载体
7. An environmentally benign and low-cost approach to synthesis of thermally stable industrial catalyst Cu/SiO2 for the hydrogenation of dimethyl oxalate to ethylene glycol [O] . Tiberiu Popa, Yulong Zhang, Erlei Jin, 2015

机译：用于合成热稳定的工业催化剂Cu / SiO2的环境良性和低成本方法，用于草酸二甲酯与乙二醇的氢化
8. Teratologic Evaluation of Ethylene Glycol Diethyl Ether (CAS No. 629-14-1) Administered to New Zealand White Rabbits on Gestational Days 6 through 19 [R] . George, J. D. , Price, C. J. , Marr, M. C. 1987

机译：新西兰白兔在妊娠第6至19天给予乙二醇二乙醚（Cas号629-14-1）的畸形评价

Synthesis of Ethylene Glycol from Syngas via OxidativeDouble Carbonylation of Ethanol to Diethyl Oxalate and Its SubsequentHydrogenation

摘要

著录项

相似文献

相关主题

期刊订阅