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Platinum and Iridium Oxide Co-modified TiO2 Nanotubes Array Based Photoelectrochemical Sensors for Glutathione

机译:谷胱甘肽的铂和铱氧化物共修饰的TiO2纳米管阵列光电化学传感器

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摘要

Oriented TiO nanotubes, which are fabricated by anodic oxidation method, are prospective in photoelectrochemical analysis and sensors. In this work, Pt and IrO co-modified TiO nanotubes array was prepared via a two-step deposition process involving the photoreductive deposition of Pt and chemical deposition of IrO on the oriented TiO nanotubes. Due to the improved separation of photo-generated electrons and holes, Pt-IrO co-modified TiO nanotubes presented significantly higher PEC activity than pure TiO nanotubes or mono-modified TiO nanotubes. The PEC sensitivity of Pt-IrO co-modified TiO nanotubes for glutathione was also monitored and good sensitivity was observed.
机译:通过阳极氧化法制备的定向TiO 2纳米管在光电化学分析和传感器中具有前景。在这项工作中,Pt和IrO共修饰的TiO纳米管阵列是通过两步沉积工艺制备的,该过程涉及Pt的光还原沉积和IrO在定向TiO纳米管上的化学沉积。由于改进了光生电子和空穴的分离,Pt-IrO共改性的TiO纳米管比纯TiO纳米管或单改性的TiO纳米管表现出明显更高的PEC活性。还监测了Pt-IrO共修饰的TiO纳米管对谷胱甘肽的PEC敏感性,并观察到良好的敏感性。

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