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Phonon Sideband Analysis and Near-Infrared Emission in Heavy Metal Oxide Glasses

机译：密码边带分析和重金属氧化物眼镜的近红外发射

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摘要

In this work, spectroscopic properties of europium and erbium ions in heavy metal oxide glasses have been studied. The phonon energy of the glass host was determined based on Eu3+ excitation spectra measurements. Near-IR emission spectra at 1550 nm related to 4I13/2 → 4I15/2 transition of erbium in heavy metal glasses were examined with special regards to luminescence bandwidth and measured lifetime. In particular, correlation between phonon energy and the measured lifetime 4I13/2 (Er3+) was proposed. The luminescence lifetime for the 4I13/2 upper laser state of erbium decreases with increasing phonon energy in glass matrices. Completely different results were obtained glass samples with europium ions, where the 5D0 lifetime increases with increasing phonon energy. Our investigations suggest that the values of measured 5D0 lifetime equal to radiative lifetimes for all heavy metal oxide glasses.

机译：在这项工作中，研究了重金属氧化物玻璃中铕和铒离子的光谱性质。基于EU3 +激发光谱测量来确定玻璃主体的声子能量。与4i13 / 2→4i15 / 2→4i15 / 2 erbium的1550nm相关的近红外发射光谱被检查在重金玻璃中的erbium erbium的过渡，并考虑到发光带宽和测量的寿命。特别地，提出了Phonon能量与测量的寿命4i13 / 2（ER3 +）之间的相关性。利用玻璃基质中的声子能量增加，4i13 / 2上激光erbium的发光寿命减少。通过铕离子获得完全不同的结果，其中5d0寿命随着旋转能量的增加而增加。我们的研究表明，测量的5d0寿命的值等于所有重金属氧化物玻璃的辐射寿命。

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期刊名称 Materials
作者
Joanna Pisarska; Wojciech A. Pisarski; Radosław Lisiecki; Witold Ryba-Romanowski;
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作者单位

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年(卷),期 2021(14),1
年度 2021
页码 121
总页数 10
原文格式 PDF
正文语种
中图分类外科学;
关键词
heavy metal glasses; phonon sideband; rare earth ions; luminescence;

机译：重金属眼镜;声子边带;稀土;发光;

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1. Luminescence and phonon sideband analysis of Eu~(3+) doped alkali fluoroborate glasses for red emission applications [J] . Subash Gopi, Saritha K. Jose, Anns George, Journal of materials science . 2018,第1期

机译：掺Eu〜（3+）的氟硼酸碱玻璃的发光和声子边带分析
2. Near-infrared emissions with widely different widths in two kinds of Er3+-doped oxide glasses with high refractive indices and low phonon energies [J] . Lin H, Tanabe S, Lin L, Journal of Luminescence . 2007,第1期

机译：在两种高折射率和低声子能的掺Er3 +的氧化物玻璃中，近红外光的宽度差异很大
3. Near-infrared emissions with widely different widths in two kinds of Er~(3+) -doped oxide glasses with high refractive indices and low phonon energies [J] . H. Lin, S. Tanabe, L. Lin, Journal of Luminescence . 2007,第1期

机译：两种高折射率和低声子能的掺Er〜（3+）氧化物玻璃的近红外发射宽度差异很大
4. Broadband Mid-Infrared Emission in Heavy Metal Oxide Glasses Triply-Doped with Er~(3+)/Ho~(3+)/Yb~(3+) Ions [C] . Tomasz Ragin, Jacek Zmojda, Marcin Kochanowicz, International Conference on Transparent Optical Networks . 2017

机译：重金属氧化物玻璃中的宽带中红外发射掺杂有ER〜（3 +）/ HO〜（3 +）/ YB〜（3+）离子
5. Determination of oxidation mechanisms of ethylenediaminetetraacetate (EDTA)-metal complexes by alkaline permanganate and structures of in situ formed manganese oxides containing heavy metals. [D] . Chang, Hyun-shik. 2007

机译：碱性高锰酸盐测定乙二胺四乙酸盐（EDTA）-金属配合物的氧化机理以及原位形成的含重金属的锰氧化物的结构。
6. Development of Dispersion-Optimized Photonic Crystal Fibers Based on Heavy Metal Oxide Glasses for Broadband Infrared Supercontinuum Generation with Fiber Lasers [O] . Grzegorz Stępniewski, Jacek Pniewski, Dariusz Pysz, 2018

机译：基于重金属氧化物玻璃的色散优化光子晶体光纤的开发用于光纤激光器产生宽带红外超连续谱
7. Phonon Sideband Analysis and Near-Infrared Emission in Heavy Metal Oxide Glasses [O] . Joanna Pisarska, Wojciech A. Pisarski, Radosław Lisiecki, 2020

机译：密码边带分析和重金属氧化物眼镜的近红外发射
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Phonon Sideband Analysis and Near-Infrared Emission in Heavy Metal Oxide Glasses

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