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Identification of Anthocyanins and Their Fouling Mechanisms during Non-Thermal Nanofiltration of Blueberry Aqueous Extracts

机译:鉴定蓝莓含水提取物非热纳米过滤期间的花青素及其污垢机制

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摘要

Organic fouling in the nanofiltration (NF) process, which is a non-thermal technology to recover active components, is a critical problem limiting its applications. This study seeks to identify the anthocyanins on the NF membrane and explore their fouling mechanisms during concentration of blueberry extracts. Seven kinds of monomeric anthocyanins in foulants—delphinidin-3-O-galactoside, delphinidin-3-O-glucoside, delphinidin-3-O-arabinoside, cyanidin-3-O-galactoside, petunidin-3-O-galactoside, peonidin-3-O-glucoside, and malvidin-3-O-glucoside—were identified. Moreover, chalcone, myricetin derivative, and an unknown substance with [M+H]+ at m/z 261.1309, which is the fragment ion corresponding to the break of glycoside bond of anthocyanins, were obtained. Interactions between anthocyanins and membrane made from polyamide were principally governed by the CH-π and π-π stacking of aromatic rings, the establishment of hydrogen bonds, and electrostatic interaction. This study will be helpful to further control fouling and choice of cleaning agents in concentration of anthocyanins-rich extracts.
机译:纳米滤波(NF)过程中的有机污染,即恢复活性组件的非热技术,是限制其应用的关键问题。该研究旨在鉴定NF膜上的花青素,并在蓝莓提取物浓缩过程中探讨它们的污垢机制。粪便器中七种单体花青素 - 德尔芬蛋白-3-O-半乳糖糖苷,德尔菲林-3-o-葡糖苷,德尔司蛋白-3-Orabinoside,Cyanidin-3-O-半乳糖糖苷,Petunidin-3-O-半乳糖糖苷,PeoNidin-鉴定了3 o-葡萄糖苷和麦类-3-O-葡糖苷 - 被鉴定出来。此外,获得了Chalcone,Myricetin衍生物和在M / Z 261.1309的[M + H] +的未知物质,其是对对应于花青素的糖苷键的断裂离子的片段离子。由聚酰胺制成的花青素和膜之间的相互作用主要由芳环的CH-π和π-π堆叠,建立氢键和静电相互作用。本研究将有助于进一步控制富含花青素的提取物的污垢和清洁剂的选择。

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