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Comparison of pesticide residues in surface water and ground water of agriculture intensive areas

机译:农业集约区地表水和地下水中农药残留的比较。

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摘要

The organochlorines (OClPs) and organophosphates (OPPs) pesticides in surface and ground water having intensive agriculture activity were investigated to evaluate their potential pollution and risks on human health. As per USEPA 8081 B method, liquid-liquid extraction followed by Gas-Chromatographic technique with electron capture detector and mass selective detector (GC-MS) were used for monitoring of pesticides. Among organochlorines, α,β,γ,δ HCH’s, aldrin, dicofol, DDT and its derivatives, α,β endosulphan’s and endosulphan-sulphate were analysed; dichlorovos, ethion, parathion-methyl, phorate, chlorpyrifos and profenofos were determined among organophosphates.As compared to ground water, higher concentrations of OClPs and OPPs were found in surface water. Throughout the monitoring study, α - HCH (0.39 μg/L in Amravati region),α - endosulphan (0.78 μg/L in Yavatmal region), chlorpyrifos (0.25 μg/L in Bhandara region) and parathion-methyl (0.09 μg/L in Amravati region) are frequently found pesticide in ground water, whereas α,β,γ-HCH (0.39 μg/L in Amravati region), α,β - endosulphan (0.42 μg/L in Amravati region), dichlorovos (0.25 μg/L in Yavatmal region), parathion-methyl (0.42 μg/L in Bhandara region), phorate (0.33 μg/L in Yavatmal region) were found in surface water.Surface water was found to be more contaminated than ground water with more number of and more concentrated pesticides. Among pesticides water samples are found to be more contaminated by organophosphate than organochlorine. Pesticides in the surface water samples from Bhandara and Yavatmal region exceeded the EU (European Union) limit of 1.0 μg/L (sum of pesticide levels in surface water) but were within the WHO guidelines for individual pesticides.
机译:调查了农业活动活跃的地表水和地下水中的有机氯(OClPs)和有机磷酸盐(OPPs)农药,以评估其对人体健康的潜在污染和风险。根据USEPA 8081 B方法,采用液-液萃取,然后采用气相色谱技术,电子捕获检测器和质量选择检测器(GC-MS)来监测农药。在有机氯中,分析了α,β,γ,δ六氯环己烷,艾氏剂,三氯杀螨醇,滴滴涕及其衍生物,α,β硫丹和硫丹硫酸盐。测定了有机磷酸酯中的敌敌畏,乙硫磷,甲基对硫磷,甲酸酯,毒死rif和非诺磷。与地下水相比,地表水中的OClPs和OPPs含量更高。在整个监测研究中,α-六氯环己烷(阿姆拉瓦蒂地区为0.39μg/ L),α-内啡肽(Yavatmal区域为0.78μg/ L),毒死rif(班达拉地区为0.25μg/ L)和甲基对硫磷(0.09μg/ L)在阿姆拉瓦蒂地区经常被发现是农药,而α,β,γ-六氯环己烷(阿姆拉瓦蒂地区为0.39μg/ L),α,β-核苷(阿姆拉瓦蒂地区为0.42μg/ L),敌敌畏(0.25μg/在地表水中发现了对硫磷,甲基对硫磷(班达拉地区为0.42μg/ L),甲酸盐(在亚瓦特马尔地区为0.33μg/ L),发现地表水比地下水受污染的程度更高,和更多浓缩农药。在农药中,发现水样品比有机氯受有机磷酸盐的污染更大。来自班达拉和雅瓦特马尔地区的地表水样品中的农药超过了欧盟(欧盟)限值1.0μg/ L(地表水中农药水平的总和),但在WHO单独农药标准范围内。

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