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β' and βprecipitation in an Al-Mg alloy studied by DSC and TEM

机译:DSC和TEM研究Al-Mg合金中的β'和β析出

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Precipiation in Al-16 at./100Mg is investigated by differential scanning calorimetry (DSC) and transmission electron microscopy(TEM). The shape of the β' formation DSC effect is interpreted with a novel theory and the curves obtained on the basis of this new theory fit well to the experimental curves. The s parameter derive from these fits, which is akin to the Avrami parameter n appearing in the John- Son-Mehl-Avrami-Kolmogorov model, is larger than 2.5, indicating that β' precipitation is an autocataly- Tic process. TEM showed the abundant presence of defects(mostly dislocation loops) but no evidence of Nucleation of β' precipitates on these defects. The enthalpies of formation of the βand β' phases are de- Rived as 15.7 and 11.5 kJ per mol Mg, respectively.
机译:通过差示扫描量热法(DSC)和透射电子显微镜(TEM)研究Al-16 at.100Mg的析出。 β'形成DSC效应的形状用新颖的理论来解释,并且基于该新理论获得的曲线与实验曲线很好地吻合。从这些拟合中得出的s参数大于2.5,类似于出现在John-Son-Mehl-Avrami-Kolmogorov模型中的Avrami参数n,该参数大于2.5,表明β'沉淀是自催化过程。 TEM显示出大量缺陷(主要是位错环)的存在,但没有证据表明在这些缺陷上有β'析出核。 β和β'相的形成焓分别为每摩尔Mg 15.7和11.5 kJ。

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