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Spectral Engineering of Semitransparent Polymer Solar Cells for Greenhouse Applications

机译:用于温室的半透明聚合物太阳能电池的光谱工程

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摘要

In this study, a wavelength selective semitransparent polymer solar cell (ST-PSC) with a proper transmission spectrum for plant growth is proposed for greenhouse applications. A ternary strategy combining a wide bandgap polymer donor with a near-infrared absorbing nonfullerene acceptor and a high electron mobility fullerene acceptor is introduced to achieve PSCs with power conversion efficiency (PCE) over 10%. The addition of PC71BM into J52:IEICO-4F binary blend contributes to the suppressed trap-assisted recombination, enhanced charge extraction, and improved open-circuit voltage simultaneously. ST-PSC based on the J52:IEICO-4F:PC71BM ternary blend shows an optimized performance with PCE of 7.75% and a defined crop growth factor of 24.8%. Such high-performance ST-PSC is achieved by carefully engineering the absorption spectrum of the light harvesting materials. As a result, the transmission spectra of the semitransparent devices are well-matched with the absorption spectra of the photoreceptors, such as chlorophylls, in green plants, which provides adequate lighting conditions for photosynthesis and plant growth, and therefore making it a competitive candidate for photovoltaic greenhouse applications.
机译:在这项研究中,针对温室应用,提出了一种具有适当透射光谱以适合植物生长的波长选择性半透明聚合物太阳能电池(ST-PSC)。引入三元策略,将宽带隙聚合物供体与吸收近红外光的富勒烯受体和高电子迁移率富勒烯受体结合,以实现功率转换效率(PCE)超过10%的PSC。在J52:IEICO-4F二元共混物中添加PC71BM有助于抑制陷阱辅助的重组,增强电荷提取并同时改善开路电压。基于J52:IEICO-4F:PC71BM三元混合物的ST-PSC表现出最佳性能,PCE为7.75%,定义的作物生长因子为24.8%。通过精心设计光收集材料的吸收光谱,可以实现这种高性能的ST-PSC。结果,半透明器件的透射光谱与绿色植物中的光感受器(例如叶绿素)的吸收光谱完全匹配,这为光合作用和植物生长提供了充足的光照条件,因此使其成为竞争的候选者。光伏温室的应用。

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  • 来源
    《Advanced energy materials》 |2019年第5期|1803438.1-1803438.8|共8页
  • 作者单位

    South China Univ Technol, State Key Lab Luminescent Mat & Devices, Inst Polymer Optoelect Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China;

    South China Univ Technol, State Key Lab Luminescent Mat & Devices, Inst Polymer Optoelect Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China;

    South China Univ Technol, State Key Lab Luminescent Mat & Devices, Inst Polymer Optoelect Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China|South China Inst Collaborat Innovat, Innovat Ctr Printed Photovolta, Dongguan 523808, Peoples R China;

    South China Univ Technol, State Key Lab Luminescent Mat & Devices, Inst Polymer Optoelect Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China|South China Inst Collaborat Innovat, Innovat Ctr Printed Photovolta, Dongguan 523808, Peoples R China;

    South China Univ Technol, State Key Lab Luminescent Mat & Devices, Inst Polymer Optoelect Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    crop growth factor; photovoltaic greenhouse; semitransparent polymer solar cells; spectral engineering;

    机译:作物生长因子;光伏温室;半透明聚合物太阳能电池;光谱工程;

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