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An Ultra-Mechanosensitive Visco-Poroelastic Polymer Ion Pump for Continuous Self-Powering Kinematic Triboelectric Nanogenerators

机译:用于连续自动运动型摩擦纳米料的超机械粘性粘弹性聚合物离子泵

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摘要

A mechanosensitive, visco-poroelastic polymer ion pump that can rapidly establish a dense electrical double layer via mechanical pressure, thereby significantly enhancing output performance of an ionic triboelectric nanogenerator (iTENG), is described. A working mechanism of an iTENG using a highly mechanosensitive, visco-poroelastic ion pump is suggested and the optimal characteristics of the polymer ion pump are reported by investigating optical, mechanical, electrical, and electrochemical properties. Surprisingly, the pressure sensitivity of the iTENG reaches 23.3 V kPa(-1), which is tens of times the record value. To achieve controlled high-frequency pulses from an iTENG, kinematic systems using a gear train and a cam are integrated with a single grounded iTENG, which produces a maximum of 600 V and 22 mA (approximate to 2.2 W cm(-2)) at an input frequency of 1.67 Hz; after power transforming, those values are converted to 1.42 V and 225 mA. A capacitor of 1 mF can be fully charged to 2 V in only 60 s, making it possible to continuously operate a wireless-communicating self-powered humidity sensor. Also, due to the high transparency and deformability of the polymer ion pump, a self-powered transparent tactile sensor is successfully assembled using a 5 x 5 iTENG array.
机译:可以通过机械压力快速建立致密的电双层的机械敏感性的粘弹性聚合物离子泵,从而显着提高离子摩擦纳米料(Iteng)的输出性能。使用高机械敏感的粘孔弹性离子泵的伊腾的工作机理,并通过研究光学,机械,电气和电化学性能来报告聚合物离子泵的最佳特性。令人惊讶的是,伊腾的压力敏感性达到23.3 V KPA(-1),这是记录值的几十倍。为了实现来自伊腾的受控高频脉冲,使用齿轮系和凸轮的运动系物与单个接地的iteng集成,其最多可达600 V和22 mA(近似为2.2W cm(-2))输入频率为1.67 Hz;电力转换后,这些值转换为1.42 V和225 mA。仅在60秒内完全充电1 MF的电容器,可以完全充电至2 V,使得可以连续地操作无线通信的自动湿度传感器。而且,由于聚合物离子泵的高透明度和可变形性,使用5×5 iteg阵列成功组装自动透明触觉传感器。

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