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Efficiency Enhancement of Polymer Solar Cells Based on Poly(3-hexylthiophene)/Indene-C70 Bisadduct via Methylthiophene Additive

机译:通过甲基噻吩添加剂提高基于聚(3-己基噻吩)/ Indene-C70双键加合物的聚合物太阳能电池的效率

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摘要

Photovoltaic performance of polymer solar cells based on poly(3-hexylthiophene) (P3HT) as the donor and indene-C70 bisadduct (IC70BA) as the acceptor is improved by adding 3 vol% 3-methylthiophene (MT) or 3-hexylthiophene (HT) as processing additives. The results of UV-vis absorption spectroscopy, X-ray diffraction analysis and atomic force microscopy indicate that with the MT or HT processing additive, the active layer of the blend of P3HT/IC70BA showed strengthened absorbance, enhanced crystallinity and improved film morphology. The power conversion efficiency (PCE) of the PSCs was improved from 5.80% for the device without the additive to 6.35% for the device with HT additive and to 6.69% with MT additive. The PCE of 6.69% is the top value reported so far for the PSCs based on P3HT.
机译:通过添加3体积%的3-甲基噻吩(MT)或3-己基噻吩(HT),可以改善基于聚(3-己基噻吩)(P3HT)作为施主和茚-C70双加合物(IC70BA)作为受体的聚合物太阳能电池的光伏性能。 )作为加工助剂。紫外可见吸收光谱,X射线衍射分析和原子力显微镜的结果表明,使用MT或HT加工添加剂,P3HT / IC70BA共混物的活性层显示出增强的吸收率,增强的结晶度和改善的膜形态。 PSC的功率转换效率(PCE)从无添加剂的设备的5.80%提高到有HT添加剂的设备的6.35%和有MT添加剂的设备的6.69%。迄今为止,基于P3HT的PSC的PCE为6.69%。

著录项

  • 来源
    《Advanced energy materials》 |2011年第6期|1-4|共4页
  • 作者单位

    Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Organic Solids Institute of Chemistry Chinese Academy of Sciences Beijing 100190 People's Republic of China Fax: (+86) 10-62559373;

    Key Laboratory of carbon fiber and functional polymers Ministry of Education Beijing University of Chemical Technology Beijing 100029 People's Republic of China;

    Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Organic Solids Institute of Chemistry Chinese Academy of Sciences Beijing 100190 People's Republic of China Fax: (+86) 10-62559373;

    Key Laboratory of carbon fiber and functional polymers Ministry of Education Beijing University of Chemical Technology Beijing 100029 People's Republic of China;

    Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Organic Solids Institute of Chemistry Chinese Academy of Sciences Beijing 100190 People's Republic of China Fax: (+86) 10-62559373;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    polymer solar cells; 3-methylthiophene additive; poly(3-hexylthiophene); indene-C70 bisadduct;

    机译:聚合物太阳能电池;3-甲基噻吩添加剂;聚(3-己基噻吩);茚-C70双加合物;

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