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Superhydrophobic, Reversibly Elastic, Moldable, and Electrospun (SupREME) Fibers with Multimodal Functions: From Oil Absorbents to Local Drug Delivery Adjuvants

机译:具有多峰功能的超疏水,可逆弹性,可模压和电纺(SupREME)纤维:从吸油剂到局部药物输送辅助剂

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Surface hydrophobicity has served as a core means for governing the spatial behaviors of numerous substances depending on their affinities to oil or aqueous phases. Exploiting systems that can maximize hydrophobic features contributes to the development of versatile supports capable of spatially separating, guiding, or protecting target materials in defined manners. Herein, superhydrophobic, reversibly elastic, moldable, and electrospun (SupREME) fibers, which exhibit multimodal functions for arranging spatial responses of substances with distinct affinities to oil phases, are fabricated by coaxially electrospinning polysulfone and poly(glycerol sebacate) (PGS), followed by a thermal process. The exterior PSF layers enable volumetric expansion of the fibers, further reinforcing the overall superhydrophobicity (contact angles > 150 degrees). The elastic core PGS networks confer reversibly compressible properties (> 100 cycles) to the fibers, ultimately enhancing their hydrophobic performance and extending their durability. The SupREME fibers demonstrate superiorities as absorbents for selectively separating oil-based substances, sealants for blocking the leakage of aqueous fluids, and adjuvants for temporarily enhancing the local residence of drugs by repelling ambient fluidic environments. The SupREME fibers can be versatile platforms in many applications that require the spatial regulation of specific substances with affinities to oil or water phases, ranging from environmental industries to medical fields.
机译:表面疏水性已成为控制许多物质根据其对油相或水相的亲和力的空间行为的核心手段。可以使疏水性特征最大化的开发系统有助于开发能够以限定方式在空间上分离,引导或保护目标材料的通用载体。在此,通过同轴电纺聚砜和聚癸二酸甘油酯(PGS)来制造超疏水,可逆弹性,可模制和电纺(SupREME)纤维,这些纤维表现出多峰功能,可安排对油相具有不同亲和力的物质的空间响应。通过热处理。外部PSF层可实现纤维的体积膨胀,从而进一步增强整体超疏水性(接触角> 150度)。弹性纤芯的PGS网络赋予纤维可逆的可压缩特性(> 100个循环),最终增强了它们的疏水性能并延长了其耐用性。 SupREME纤维具有优越的优势,可以用作选择性分离油基物质的吸收剂,用于阻止水性流体泄漏的密封剂,以及用于通过排斥周围流体环境来暂时增强药物局部滞留的助剂。 SupREME纤维可以在许多应用中用作通用平台,这些应用需要对与油或水相具有亲和力的特定物质进行空间调节,从环境行业到医疗领域。

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