Electrostatic Anchoring of Mn_4 Single-Molecule Magnets onto Chemically Modified Multiwalled Carbon Nanotubes

Concha Bosch-Navarro; Eugenio Coronado; Carlos Marti-Gastaldo; Benito Rodriguez-Gonzalez; Luis M. Liz-Marzan

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Electrostatic Anchoring of Mn_4 Single-Molecule Magnets onto Chemically Modified Multiwalled Carbon Nanotubes

机译：Mn_4单分子磁体在化学修饰的多壁碳纳米管上的静电锚定

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Two different routes that enable the electrostatic grafting of cationic single-molecule magnets (SMMs) onto the surface of chemically modified anionic multi-walled carbon nanotubes (MWNTs) are described. The chemical nature and physical properties of the resulting hybrids are discussed on the basis of a complete battery of experimental techniques. The data show that the chemical nature of the SMM unit remains intact, while its magnetic response is significantly affected by the grafting process, which is likely due to surface effects.

机译：描述了两种使阳离子单分子磁体（SMM）静电接枝到化学修饰的阴离子多壁碳纳米管（MWNT）表面上的途径。在完整的实验技术基础上讨论了所得杂化物的化学性质和物理性质。数据表明，SMM单元的化学性质保持不变，而其磁响应受接枝过程的影响很大，这很可能是由于表面效应所致。

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《Advanced Functional Materials》 |2012年第5期|p.979-988|共10页
作者
Concha Bosch-Navarro; Eugenio Coronado; Carlos Marti-Gastaldo; Benito Rodriguez-Gonzalez; Luis M. Liz-Marzan;
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Universidad de Valencia (ICMol) Catedratico Jose Beltran-2, 46980, Paterna, Spain;

Universidad de Valencia (ICMol) Catedratico Jose Beltran-2, 46980, Paterna, Spain;

Universidad de Valencia (ICMol) Catedratico Jose Beltran-2, 46980, Paterna, Spain,Department of Chemistry, University of Liverpool,Crown Street, L697ZD, Liverpool, UK;

Departamento de Qufmica-Fisica Universidade de Vigo 36310, Vigo, Spain;

Departamento de Qufmica-Fisica Universidade de Vigo 36310, Vigo, Spain;

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Electrostatic Anchoring of Mn_4 Single-Molecule Magnets onto Chemically Modified Multiwalled Carbon Nanotubes

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