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Synthesis of Semiconducting Functional Materials in Solution: From II-VI Semiconductor to Inorganic-Organic Hybrid Semiconductor Nanomaterials

机译:溶液中半导体功能材料的合成:从II-VI半导体到无机有机混合半导体纳米材料

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摘要

This Feature Article provides a brief overview of the latest development and emerging new synthesis solution strategies for II-VI semiconducting nanomaterials and inorganic-organic semiconductor hybrid materials. Research on the synthesis of II-VI semiconductor nanomaterials and inorganic-organic hybrid semiconducting materials via solution strategies has made great progress in the past few years. A variety of II-VI semiconductor and a new family of [MQ(L)_(0.5)] (M = Mn, Zn, Cd; Q = S, Se, Te; L = diamine, deta) hybrid nanostructures can be generated using solution synthetic routes. Recent advances have demonstrated that the solution strategies in pure solvent and a mixed solvent can not only determine the crystal size, shape, composition, structure and assembly properties, but also the crystallization pathway, and act as a matrix for the formation of a variety of different II-VI semiconductor and hybrid nanocomposites with diverse morphologies. These II-VI semiconductor nanostructures and their hybrid nanocomposites display obvious quantum size effects, unique and tunable optical properties.
机译:这篇专题文章简要概述了II-VI型半导体纳米材料和无机-有机半导体杂化材料的最新发展和新兴的合成解决方案策略。近年来,通过溶液策略合成II-VI族半导体纳米材料和无机-有机杂化半导体材料的研究取得了很大进展。可以生成多种II-VI半导体和新的[MQ(L)_(0.5)]系列(M = Mn,Zn,Cd; Q = S,Se,Te; L =二胺,deta)杂化纳米结构使用溶液合成路线。最近的进展表明,在纯溶剂和混合溶剂中的溶液策略不仅可以确定晶体的尺寸,形状,组成,结构和组装特性,而且还可以确定其结晶途径,并且可以作为形成各种分子筛的基质。具有不同形态的不同II-VI半导体和杂化纳米复合材料。这些II-VI半导体纳米结构及其杂化纳米复合材料显示出明显的量子尺寸效应,独特且可调谐的光学特性。

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