Photochromic Switches Incorporated in Bridging Ligands: A New Tool to Modulate Energy-Transfer Processes

Peter Belser; Luisa De Cola; Frantisek Hartl; Vincenzo Adamo; Biljana Bozic; Yoel Chriqui; Vijay Mahadevan Iyer; Ron T. F. Jukes; Joel Kuehni; Manel Querol

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Photochromic Switches Incorporated in Bridging Ligands: A New Tool to Modulate Energy-Transfer Processes

机译：桥接配体中的光致变色开关：一种用于调节能量转移过程的新工具

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The thoughful construction of molecular switches has led to a gamut of supramolecular systems that can be used in molecular electronics. These include molecules based on thienylethenes, spiropyrans, fulgides, dithienylphenanthrolines, and diazafluorenes. This article reviews the recent developments made in the synthesis and characterization of all these systems, thereby allowing a comparative study to validate the viability of these switchable molecules on a nanoscale. Also, the drawbacks of each class are demonstrated and, at the same time, the remedies for further improvisation are prescribed. We have made an honest attempt to present an exhaustive account of all the different photochromic switches developed by us hitherto.

机译：分子开关的周全结构导致了可以在分子电子学中使用的超分子系统。这些包括基于噻吩基乙烯，螺并吡喃，全氟醚，二噻吩基菲咯啉和二氮杂芴的分子。本文回顾了所有这些系统的合成和表征方面的最新进展，从而允许进行比较研究以验证这些可转换分子在纳米级上的可行性。此外，还展示了每个类别的缺点，同时规定了进一步即兴创作的补救措施。我们进行了诚实的尝试，以详尽介绍迄今为止我们开发的所有不同的光致变色开关。

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来源
《Advanced Functional Materials》 |2006年第2期|p.195-208|共14页
作者
Peter Belser; Luisa De Cola; Frantisek Hartl; Vincenzo Adamo; Biljana Bozic; Yoel Chriqui; Vijay Mahadevan Iyer; Ron T. F. Jukes; Joel Kuehni; Manel Querol;
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Department of Chemistry, University of Fribourg Chemin du Musee 9 CH-1700 Fribourg (Switzerland);

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正文语种 eng
中图分类无线电电子学、电信技术;
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1. Unsymmetrical photochromic bithienylethene-bridge tetraphenylethene molecular switches:Synthesis,aggregation-induced emission and information storage [J] . Liangwei Ma, Chengpeng Li, Qing Yan, 中国化学快报（英文版） . 2020,第002期

机译：不对称光致变色联苯乙烯桥四苯乙烯分子开关：合成，聚集诱导的发射和信息存储
2. Light switches the ligand! photochromic azobenzene-phosphanes [J] . Segarra-Maset M.D., Van Leeuwen P.W.N.M., Freixa Z. European journal of inorganic chemistry . 2010,第14期

机译：灯光切换配体！光致变色偶氮苯膦
3. Synthesis, Structures, and Magnetic Properties of Two Coordination Assemblies of Mn(III) Single Molecule Magnets Bridged via Photochromic Diarylethene Ligands [J] . Fetoh Ahmed, Cosquer Goulven, Morimoto Masakazu, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2019,第4期

机译：通过光致变色二芳基配体桥接Mn（III）单分子磁体的两个配合组件的合成，结构和磁性
4. Stability of Multilane Input-Buffered Switches with Markov-Modulated Arrival Processes [C] . Philip Ho, David Tse, jean Walrand Annual allerton conference on communication, control, and computing . 1999

机译：具有马尔可夫调制的到达过程的多通道输入缓冲开关的稳定性
5. Luminescent probes and photochromic switches based on semiconductor quantum dots [D] . Yildiz, Ibrahim 2008

机译：基于半导体量子点的发光探针和光致变色开关
6. Molecular Switches on mGluR Allosteric Ligands That Modulate Modes of Pharmacology [O] . Michael R. Wood, Corey R. Hopkins, John T. Brogan, -1

机译：分子开关上谷氨酸受体变构配体其药理调制模式
7. Electron Injection and Energy-Transfer Properties of Spiropyran–Cyclodextrin Complexes Coated onto Metal Oxide Nanoparticles: Toward Photochromic Light Harvesting [O] . Viktoras Dryza, Evan J. Bieske 2015

机译：螺旋吡喃 - 环糊精配合物涂覆在金属氧化物纳米粒子上的电子注射和能量 - 转移性能：朝向光致变色光收割机
8. Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 90. (1) Synthesis of the Complexes (W2M2(mu-CO)(mu-CMe)(mu3-CMe)-(Mu-PPh2)2(CO)3(eta-C5H5)2) (M = Rh or Ir) and Related Tetra- and Penta-nuclear Metal Compounds: Interconversion of Ketenyl and Lambda(5) -Phospha-alkyne Ligands Bridging Tungsten-Rhodium Bonds. [R] . Davies, S. J., Stone, F. G. 1989

机译：具有桥接卡宾或卡宾配体的多核金属配合物的化学。部分90.（1）配合物的合成（W2m2（mu-CO）（mu-Cme）（mu3-Cme） - （mu-pph2）2（CO）3（eta-C5H5）2）（m = Rh或Ir）和相关的四核和五核金属化合物：Ketenyl和Lambda（5）-phospha-alkyne配体桥联钨 - 铑键的相互转化。

Photochromic Switches Incorporated in Bridging Ligands: A New Tool to Modulate Energy-Transfer Processes

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