Self-assembly of m-diethynylbenzene macrocycles containing exoannular chiral side chains

Tobe Y; Nagai T; Araki S; Ichikawa T; Nomoto A; Sonoda M; Hirose K

首页> 外文期刊>Advanced Functional Materials >Self-assembly of m-diethynylbenzene macrocycles containing exoannular chiral side chains

【24h】

Self-assembly of m-diethynylbenzene macrocycles containing exoannular chiral side chains

机译：含环外手性侧链的间二乙炔苯大环的自组装

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Induced circular dichroism (CD) spectra of the m-diethynylbenzene macrocycles (S)-2 and (R)-2 that have exoannular chiral side chains are observed in a methanol/chloroform (8:2) solution, indicating the formation of chiral, helical aggregates in solution. Solid films prepared on the surface of quartz substrates by spin-coating solutions of (S)-2 also exhibit CD signals that are remarkably dependent on the solvent used for the spin-coating. The relationship between the CD spectra and the morphology of the solid films observed by atomic force microscopy is discussed.

机译：在甲醇/氯仿（8：2）溶液中观察到具有环外手性侧链的间二乙炔基苯大环（S）-2和（R）-2的诱导圆二色性（CD）光谱，表明形成了手性，溶液中的螺旋状聚集体。通过（S）-2的旋涂溶液在石英衬底的表面上制备的固体膜也表现出CD信号，该CD信号明显取决于旋涂所用的溶剂。讨论了通过原子力显微镜观察到的CD光谱与固体膜形态之间的关系。

著录项

来源
《Advanced Functional Materials》 |2006年第12期|p. 1549-1554|共6页
作者
Tobe Y; Nagai T; Araki S; Ichikawa T; Nomoto A; Sonoda M; Hirose K;
展开▼
作者单位

Osaka Univ, Grad Sch Engn Sci, Div Frontier Mat Sci, Toyonaka, Osaka 5608531, Japan;

Japan Sci & Technol Agcy, CREST, Toyonaka, Osaka 5608531, Japan;

Univ Osaka Prefecture, Fac Engn, Dept Appl Chem, Osaka 5998531, Japan;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无线电电子学、电信技术;
关键词
PHENYLENE ETHYNYLENE OLIGOMERS; PI-PI-INTERACTIONS; SHAPE-PERSISTENT; CHIROPTICAL PROPERTIES; ASSOCIATION BEHAVIOR; SOLDIERS PRINCIPLE; AGGREGATION; ARCHITECTURES; SEXITHIOPHENES; POLYTHIOPHENES;

机译：苯乙炔低聚物;PI-PI相互作用;形状持久性;化学性质;缔合行为;溶剂原理;聚集;体系结构;六苯并菲;多酚;

相似文献

外文文献
中文文献
专利

1. Self-assembly of chiral coordination polymers and macrocycles: A metal template effect on the polymer-macrocycle equilibrium [J] . Burchell TJ, Puddephatt RJ Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2005,第10期

机译：手性配位聚合物和大环化合物的自组装：金属模板对聚合物-大环化合物平衡的影响
2. Hydrophobically driven chiral column aggregates of hydrazide macrocycles and side chains-controlled chirality conversion [J] . Guo Rong, Wang Hui, Zhang Dan-Wei, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2016,第31期

机译：酰肼大环的疏水驱动手性柱聚集体和侧链控制的手性转化
3. From Foldable Open Chains to Shape-Persistent Macrocycles: Synthesis, Impact on 2D Ordering, and Stimulated Self-Assembly [J] . Soobin Kim, Henry D. Castillo, Milim Lee, Journal of the American Chemical Society . 2018,第13期

机译：从可折叠的开链到形状持久的大环：合成，对2D排序的影响以及受刺激的自组装
4. LANGMUIR-SCHAEFER FILMS OF A NEW CALIX4PYRROLE-BASED MACROCYCLE EXHIBITING INDUCED CHIRALITY UPON DIFFERENTIATED BINDING WITH CHIRAL ALCOHOL VAPOURS [C] . S. SORTINO, S. PETRALIA, B. PIGNATARO, Sensors and Microsystems . 2004

机译：一种新的杯4吡咯为基的手性醇与手性醇的差分键合诱导的手性的Langmuir-Schaefer膜
5. Utilization of the beta-Lactum Core Towards the Preparation of Chiral Ring-Fused Lactams and Preparation and Application of Synthetic Peptide Libraries Toward the Discovery and Understanding of Membrane-Permeable Macrocycles. [D] . Hewitt, William Merton. 2014

机译：β-乳芯对手性环融合内酰胺的制备的利用以及合成肽文库的制备和应用对膜可渗透大环化合物的发现和理解。
6. From the Cover: Twisting macromolecular chains: Self-assembly of a chiral supermolecule from nonchiral polythiophene polyanions and random-coil synthetic peptides [O] . K. Peter R. Nilsson, Johan Rydberg, Lars Baltzer, 2004

机译：从封面开始：扭曲大分子链：非手性聚噻吩聚阴离子和无规螺旋合成肽手性超分子的自组装
7. Self-Assembly of Chiral Coordination Polymers and Macrocycles: A Metal Template Effect on the Polymer-Macrocycle Equilibrium [O] . -1

机译：手性配位聚合物和宏细胞的自组装：对聚合物 - 宏循环平衡的金属模板效应

Self-assembly of m-diethynylbenzene macrocycles containing exoannular chiral side chains

摘要

著录项

相似文献

相关主题

期刊订阅