Indigo - A Natural Pigment for High Performance Ambipolar Organic Field Effect Transistors and Circuits

Mihai Irimia-Vladu; Eric D. Ghwacki; Pavel A. Troshin; Gunther Schwabegger; Lucia Leonat; Diana K. Susarova; Olga Krystal; Mujeeb Ullah; Yasin Kanbur; Marius A. Bodea; Vladimir F. Razumov; Helmut Sitter; Siegfried Bauer; Niyazi Serdar Sariciftci

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Indigo - A Natural Pigment for High Performance Ambipolar Organic Field Effect Transistors and Circuits

机译：靛蓝-用于高性能双极性有机场效应晶体管和电路的天然颜料

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Ambipolar charge transport in organic semiconductors is essential for the development of integrated microelectronic organic circuits and optoelectronic devices. Widespread applications are currently hampered by the narrow choice of organic materials available. Herein we report on a "new" ambipolar organic semiconductor: the centuries-old natural dye indigo. Indigo is an intrinsically ambipolar organic semiconductor with a bandgap of 1.7 eV, high and well-balanced electron and hole mobilities of 1 × 10~(-2) cm~2 V~(-1) s~(-1) and good stability against degradation in air. Indigo-based organic field-effect transistors (OFETs) and inverters have been fabricated on natural shellac resin substrates. Inverters with high gains of 105 in the first and 110 in the third quadrant are demonstrated.

机译：有机半导体中的双极性电荷传输对于集成微电子有机电路和光电器件的开发至关重要。当前，广泛的应用受到可用有机材料选择范围的限制。在这里，我们报道了一种“新的”双极性有机半导体：具有数百年历史的天然染料靛蓝。靛蓝是本征双极性有机半导体，其带隙为1.7 eV，电子和空穴迁移率达到1×10〜（-2）cm〜2 V〜（-1）s〜（-1）且平衡良好，并且具有良好的稳定性防止空气降解。基于靛蓝的有机场效应晶体管（OFET）和反相器已在天然紫胶树脂基板上制造。展示了在第一象限中具有105的高增益，在第三象限中具有110的高增益的逆变器。

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《Advanced Materials》 |2012年第3期|p.375-380|共6页
作者
Mihai Irimia-Vladu; Eric D. Ghwacki; Pavel A. Troshin; Gunther Schwabegger; Lucia Leonat; Diana K. Susarova; Olga Krystal; Mujeeb Ullah; Yasin Kanbur; Marius A. Bodea; Vladimir F. Razumov; Helmut Sitter; Siegfried Bauer; Niyazi Serdar Sariciftci;
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Soft Matter Physics Johannes Kepler University Linz Altenberger Strafe 69, 4040 Linz, Austria,Linz Institute for Organic Solar Cells Physical Chemistry Johannes Kepler University Linz Altenberger Strafe 69, 4040 Linz, Austria;

Linz Institute for Organic Solar Cells Physical Chemistry Johannes Kepler University Linz Altenberger Strafe 69, 4040 Linz, Austria;

Institute for Problems of Chemical Physics of Russian Academy of Sciences Semenov Prospect 5, Chernogolovka, Moscow region 142432,Russian Federation;

Institute of Solid State Physics Johannes Kepler University Linz Altenberger Strafe 69, 4040 Linz, Austria;

Politehnica University of Bucharest Faculty of Applied Chemistry and Materials Science Bucharest, Romania;

Institute for Problems of Chemical Physics of Russian Academy of Sciences Semenov Prospect 5, Chernogolovka, Moscow region 142432,Russian Federation;

Institute for Problems of Chemical Physics of Russian Academy of Sciences Semenov Prospect 5, Chernogolovka, Moscow region 142432,Russian Federation;

Institute of Solid State Physics Johannes Kepler University Linz Altenberger Strafe 69, 4040 Linz, Austria;

Department of Polymer Science and Technology Middle East Technical University Balgat, Ankara, Turkey;

Institute of Applied Physics Johannes Kepler University Linz Altenberger Strafe 69, 4040 Linz, Austria;

Institute for Problems of Chemical Physics of Russian Academy of Sciences Semenov Prospect 5, Chernogolovka, Moscow region 142432,Russian Federation;

Institute of Solid State Physics Johannes Kepler University Linz Altenberger Strafe 69, 4040 Linz, Austria;

Soft Matter Physics Johannes Kepler University Linz Altenberger Strafe 69, 4040 Linz, Austria;

Linz Institute for Organic Solar Cells Physical Chemistry Johannes Kepler University Linz Altenberger Strafe 69, 4040 Linz, Austria;

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1. Controlling Ambipolar Charge Transport in Isoindigo-Based Conjugated Polymers by Altering Fluorine Substitution Position for High-Performance Organic Field-Effect Transistors [J] . Kim Minjun, Park Won-Tae, Park Sang Ah, Advanced Functional Materials . 2019,第10期

机译：通过更改高性能有机场效应晶体管的氟取代位置，控制基于靛蓝的共轭聚合物中的双极电荷传输。
2. High performance ambipolar organic field-effect transistors based on indigo derivatives [J] . Oratai Pitayatanakul, Toshiki Higashino, Tomofumi Kadoya Journal of Materials Chemistry, C. materials for optical and electronic devices . 2014,第43期

机译：基于靛蓝衍生物的高性能双极性有机场效应晶体管
3. Simple Bar-Coating Process for Large-Area, High-Performance Organic Field-Effect Transistors and Ambipolar Complementary Integrated Circuits [J] . Dongyoon Khim, Hyun Han, Kang-Jun Baeg, Advanced Materials . 2013,第31期

机译：大面积，高性能有机场效应晶体管和双极互补集成电路的简单棒涂工艺
4. Bar-coated polymer ambipolar field-effect transistors and complementary integrated circuits for large area electronics [C] . Khim Dongyoon, Kim Dong-Yu, Noh Yong-Young International Workshop on Active-Matrix Flatpanel Displays and Devices . 2014

机译：棒涂聚合物双极场效应晶体管和用于大面积电子设备的互补集成电路
5. Unipolar n- and p-channel Organic Field-Effect Transistors from Solution-Processable Ambipolar Semiconducting Polymers [D] . Ford, Michael 2018

机译：溶液可加工双极性半导体聚合物的单极n沟道和p沟道有机场效应晶体管
6. Reconfigurable Complementary Logic Circuits with Ambipolar Organic Transistors [O] . Hocheon Yoo, Matteo Ghittorelli, Edsger C. P. Smits, -1

机译：具有双极性有机晶体管的可重配置互补逻辑电路
7. High performance ambipolar organic field-effect transistors based on indigo derivatives [O] . Oratai Pitayatanakul, Toshiki Higashino, Tomofumi Kadoya, 2014

机译：基于Indigo衍生物的高性能Ambipolar有机场效应晶体管

Indigo - A Natural Pigment for High Performance Ambipolar Organic Field Effect Transistors and Circuits

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