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Engineering Homochiral Metal-Organic Frameworks for Heterogeneous Asymmetric Catalysis and Enantioselective Separation

机译：异构不对称催化和对映选择性分离的工程手性金属有机骨架

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摘要

Owing to the potential applications in technological areas such as gas storage, catalysis, separation, sensing and nonlinear optics, tremendous efforts have been devoted to the development of porous metal-organic frameworks (MOFs) over the past ten years. Homochiral porous MOFs are particularly attractive candidates as heterogeneous asymmetric catalysts and enantioselective adsorbents and separators for production of optically active organic compounds due to the lack of homochiral inorganic porous materials such as zeolites. In this review, we summarize the recent research progress in homochiral MOF materials, including their synthetic strategy, distinctive structural features and latest advances in asymmetric heterogeneous catalysis and enantioselective separation.
机译：由于在气体存储，催化，分离，传感和非线性光学等技术领域的潜在应用，在过去的十年中，人们为开发多孔金属有机骨架（MOF）做出了巨大的努力。由于缺少诸如沸石的均手性无机多孔材料，作为用于生产旋光有机化合物的非均相不对称催化剂和对映选择性吸附剂和分离剂，手性多孔MOF特别吸引人。在这篇综述中，我们总结了同手性MOF材料的最新研究进展，包括其合成策略，独特的结构特征以及不对称多相催化和对映选择性分离的最新进展。

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  • 来源
    《Advanced Materials》 |2010年第37期|p.4112-4135|共24页
  • 作者

    Yan Liu; Weimin Xuan; Yong Cui;

  • 作者单位

    School of Chemistry and Chemical Technology and State Key Laboratory of Metal Matrix Composites Shanghai Jiao Tong University 800 Dongchuan Rd, Shanghai 200240 (China);

    School of Chemistry and Chemical Technology and State Key Laboratory of Metal Matrix Composites Shanghai Jiao Tong University 800 Dongchuan Rd, Shanghai 200240 (China);

    School of Chemistry and Chemical Technology and State Key Laboratory of Metal Matrix Composites Shanghai Jiao Tong University 800 Dongchuan Rd, Shanghai 200240 (China);

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