High Field-Effect Mobilities for Diblock Copolymers of Poly(3-hexylthiophene) and Poly (methyl acrylate)

Genevieve Sauve; Richard D. McCullough

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High Field-Effect Mobilities for Diblock Copolymers of Poly(3-hexylthiophene) and Poly (methyl acrylate)

机译：聚（3-己基噻吩）和聚（丙烯酸甲酯）的二嵌段共聚物的高场效应迁移率

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The use of organic semiconductors in thin-film transistors holds great promise, with applications ranging from drivers for flat-panel displays to smart cards and electronic identification tags. In particular, solution-processable organic semiconductors make it easy and cost-effective to fabricate large-area thin films using established printing technologies. Because of its high hole mobility and ease of synthesis, regioregular poly(3-hexylthiophene) (rr-P3HT) is one of the most promising and most studied solution-processable materials. To further improve the properties of rr-P3HT, we have been developing novel block copolymers of rr-P3HT. By varying the nonconjugated segment it is possible to fine-tune the physical and electrical properties of the copolymer for various device applications. To assess the electrical properties of our block copolymers we previously measured conductivities of iodine-doped films using the 4-point probe method.

机译：在薄膜晶体管中使用有机半导体具有广阔的前景，其应用范围从平板显示器的驱动器到智能卡和电子识别标签。特别地，可溶液处理的有机半导体使得使用既定的印刷技术来制造大面积薄膜变得容易且具有成本效益。由于它的高空穴迁移率和易于合成，区域规则的聚（3-己基噻吩）（rr-P3HT）是最有前途和研究最多的可溶液加工材料之一。为了进一步提高rr-P3HT的性能，我们一直在开发rr-P3HT的新型嵌段共聚物。通过改变非共轭链段，可以针对各种装置应用微调共聚物的物理和电学性质。为了评估我们的嵌段共聚物的电性能，我们先前使用4点探针法测量了碘掺杂薄膜的电导率。

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《Advanced Materials》 |2007年第14期|1822-1825|共4页
作者
Genevieve Sauve; Richard D. McCullough;
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Department of Chemistry, Carnegie Mellon University Pittsburgh, PA 15213 (USA);

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正文语种 eng
中图分类工程材料学;
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1. High Field-Effect Mobilities for Diblock Copolymers of Poly(3-hexylthiophene) and Poly(methyl acrylate) [J] . Genevieve Sauve, Richard D. McCullough Advanced Materials . 2007,第14期

机译：聚（3-己基噻吩）和聚（丙烯酸甲酯）的二嵌段共聚物的高场效应迁移率
2. Synthesis and characterization of diblock copolymers based on poly(3-hexylthiophene) and photo-responsive poly(methyl methacrylate-random-2-methyl methaspirooxazine) [J] . Ha Tran Nguyen, Nguyen Le-Thu T., Thang Van Le Designed Monomers and Polymers: An International Journal on Monomer and Macromolecular Synthesis . 2015,第3期

机译：基于聚（3-己基噻吩）和光敏性聚（甲基丙烯酸甲酯-无规-2-甲基甲基螺恶嗪）的二嵌段共聚物的合成与表征
3. Synthesis and characterization of diblock copolymers based on poly(3-hexylthiophene) and photo-responsive poly(methyl methacrylate-random-2-methyl methaspirooxazine) [J] . Ha Tran Nguyen, Le-Thu T. Nguyen, Thang Van Le Designed Monomers and Polymers . 2015,第3期

机译：基于聚（3-己基噻吩）和光敏性聚（甲基丙烯酸甲酯-无规-2-甲基甲基螺恶嗪）的二嵌段共聚物的合成与表征
4. Synthesis, mobility, and conductivity of well-defined regioregular poly(3-hexylthiophene) and diblock copolymers of regioregular poly(3-hexylthiophene) [C] . Genevieve Sauve, Rui Zhang, Shijun Jia, Organic Field-Effect Transistors V . 2006

机译：定义明确的区域规则的聚（3-己基噻吩）和区域规则的聚（3-己基噻吩）的二嵌段共聚物的合成，迁移率和电导率
5. The physical and spectroscopic study of a series of poly(3-hexyl thiophene) homopolymers and poly(3-hexyl thiophene)-block-poly(2-hydroxyethyl methacrylate) diblock copolymers. [D] . Peng, Qiliang. 2010

机译：一系列聚（3-己基噻吩）均聚物和聚（3-己基噻吩）-嵌段-聚（甲基丙烯酸2-羟乙酯）二嵌段共聚物的物理和光谱研究。
6. Enhancement of field-effect mobility due to structural ordering in poly(3-hexylthiophene) films by the dip-coating technique [O] . Kamran Ali, Ullrich Pietsch, Souren Grigorian -1

机译：通过浸涂技术增强聚（3-己基噻吩）薄膜中的结构有序性从而提高场效应迁移率
7. Synthesis of Poly(n-butyl acrylate)-block-poly(acrylic acid) Diblock Copolymers by ATRP and Their Micellization in Water [O] . -1

机译：用ATRP及其在水中的晶粒子合成聚（正丁基丙烯酸丙烯酸酯）二嵌段共聚物的聚（正丁基酯）二嵌段共聚物
8. Light Scattering Studies of Poly(methyl Methacrylate)/(Poly(ethyl Acrylate)/Poly(butyl Acrylate)) Terpolymer [R] . Chu, B., Ying, Q., Lee, D. C., 1985

机译：聚甲基丙烯酸甲酯/（聚（丙烯酸乙酯）/聚（丙烯酸丁酯））三元共聚物的光散射研究

High Field-Effect Mobilities for Diblock Copolymers of Poly(3-hexylthiophene) and Poly (methyl acrylate)

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