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Zn and ZnO nanoparticles fabricated by ion implantation combined with thermal oxidation, and the defect-free luminescence

机译:离子注入结合热氧化制备的Zn和ZnO纳米粒子,无缺陷发光

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摘要

Silica glass implanted with Zn ions of 60 keV to 1.0 X 10~(17) ions/cm~2 was annealed in oxygen gas to form ZnO nanoparticles (NPs). In as-implanted state, the implanted Zn atoms form Zn metallic NPs inside of the silica. After annealing at 600 ℃, ZnO NPs form on the surface, while Zn metallic NPs still remain in the deep region. At 700 ℃, most of Zn atoms move to the surface to form the droplet-shaped ZnO NPs which show two photoluminescence bands, i.e., an exciton band at 375 nm and a defect band at ~500 nm. The defect band almost disappears in the samples annealed at 600 ℃, which include both ZnO NPs and Zn NPs.
机译:在氧气中退火注入60 keV到1.0 X 10〜(17)离子/ cm〜2的Zn离子的石英玻璃,以形成ZnO纳米粒子(NPs)。在注入状态下,注入的Zn原子在二氧化硅内部形成Zn金属NP。经过600℃退火后,ZnO NPs在表面形成,而Zn金属NPs仍保留在较深的区域。在700℃时,大部分的Zn原子移动到表面,形成了液滴状的ZnO NPs,具有两个光致发光带,即375 nm的激子带和〜500 nm的缺陷带。在600℃退火的样品中,ZnO NPs和Zn NPs的缺陷带几乎消失。

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