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Recycling of phenol from aqueous solutions by pervaporation with ZSM-5/PDMS/PVDF hollow fiber composite membrane

机译:通过ZSM-5 / PDMS / PVDF中空纤维复合膜的渗透蒸发从水溶液中回收苯酚

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摘要

Zeolite (ZSM-5)/polydimethylsiloxane (PDMS)/polyvinylidene fluoride (PVDF) hollow fiber composite membrane was prepared by dynamic negative pressure. The influence of ZSM-5 silanization, coating time and concentration of ZSM-5 on the resulting pervaporation (PV) performance of composite membranes was investigated. The contact angle (CA) was used to measure surface hydrophobic property and it was found that the water contact angle of the membrane was increased significantly from 99 degrees to 132 degrees when the concentration of ZSM-5 increased from 0% to 50%. The morphology of the membrane was characterized by scanning electron microscope (SEM) and those SEM images illustrated that the thickness of the separating layer has obvious differences at varying coating times. Furthermore, the membranes were investigated in PV process to recycle phenol from aqueous solutions as feed mixtures. The impact of phenol concentration in feed, temperature and pressure of penetration side on the PV performance of membrane was studied systematically. When the ZSM-5 concentration was 40% and the coating time was 60 min, separation factor and phenol permeability were 4.56 and 5.78 g/(m(2) h), respectively. ZSM-5/PDMS/PVDF membrane significantly improved the recovery efficiency of phenols. (C) 2017 Published by Elsevier B.V.
机译:通过动态负压制备了沸石(ZSM-5)/聚二甲基硅氧烷(PDMS)/聚偏氟乙烯(PVDF)中空纤维复合膜。研究了ZSM-5硅烷化,涂布时间和ZSM-5浓度对所得复合膜全透(PV)性能的影响。接触角(CA)用于测量表面疏水性,并且发现当ZSM-5的浓度从0%增加到50%时,膜的水接触角从99度显着增加到132度。膜的形貌通过扫描电子显微镜(SEM)表征,并且这些SEM图像表明,在不同的涂布时间下,隔离层的厚度具有明显的差异。此外,对膜进行了PV工艺研究,以从水溶液中回收苯酚作为进料混合物。系统研究了进料中苯酚的浓度,渗透侧的温度和压力对膜PV性能的影响。当ZSM-5浓度为40%,涂布时间为60分钟时,分离系数和苯酚渗透率分别为4.56和5.78 g /(m(2)h)。 ZSM-5 / PDMS / PVDF膜显着提高了苯酚的回收效率。 (C)2017由Elsevier B.V.发布

著录项

  • 来源
    《Applied Surface Science》 |2018年第ptab期|288-297|共10页
  • 作者单位

    Harbin Inst Technol, Sch Environm, Harbin 150090, Heilongjiang, Peoples R China;

    Harbin Inst Technol, Sch Environm, Harbin 150090, Heilongjiang, Peoples R China|Natl Engn Ctr Urban Water Resources, 202 Hehai Rd, Harbin 150090, Heilongjiang, Peoples R China;

    Harbin Inst Technol, Sch Environm, Harbin 150090, Heilongjiang, Peoples R China;

    Harbin Inst Technol, Sch Environm, Harbin 150090, Heilongjiang, Peoples R China;

    Evides Ind Water BV, Schaardijk 150, NL-3063 NH Rotterdam, Netherlands;

    Evides Ind Water BV, Schaardijk 150, NL-3063 NH Rotterdam, Netherlands;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    PVDF hollow fiber membranes; Modification; Pervaporation; Phenols;

    机译:PVDF中空纤维膜;改性;全蒸发;酚;

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