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Mn-coatings on the micro-pore formed Ti-29Nb-xHf alloys by RF-magnetron sputtering for dental applications

机译:射频磁控溅射在微孔形成的Ti-29Nb-xHf合金上的锰涂层在牙科领域的应用

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In this study, Mn-coatings on the micro-pore formed Ti-29Nb-xHf alloys by RF-magnetrons sputtering for dental applications were studied using different experimental techniques. Mn coating films were formed on Ti-29Nb-xHf alloys by a radio frequency magnetron sputtering technique for 0, 1, 3, and 5 min at 45 W. The microstructure, composition, and phase structure of the coated alloys were examined by optical microscopy, field emission scanning electron microscopy, X-ray diffraction, and energy-dispersive X-ray spectroscopy. The microstructure of Ti-29Nb alloy showed alpha phase in the needle-like structure and Ti-29Nb-15Hf alloy showed beta phase in the equiaxed structure. As the sputtering time increased, the circular particles of Mn coatings on the Ti-29Nb alloy increased at inside and outside surfaces. As the sputtering time increased, [Mn + Ca/P] ratio of the plasma electrolytic oxidized films in Ti-29Nb-xHf alloys increased. The corrosion potential (Ecorr) of Mn coatings on the Ti-29Nb alloy showed higher than that of Mn coatings on the Ti-29Nb-15Hf alloy. The passive current density (I-pass) of the Mn coating on the Ti-29Nb alloy and Mn coatings on the Ti-29Nb-15Hf alloy was less noble than the non-Mn coated Ti-29Nb and Ti-29Nb-15Hf alloys surface. (C) 2017 Elsevier B.V. All rights reserved.
机译:在这项研究中,使用不同的实验技术研究了通过射频磁控溅射在微孔形成的Ti-29Nb-xHf合金上用于牙科的Mn涂层。在45 W下通过射频磁控溅射技术在Ti-29Nb-xHf合金上形成0、1、3和5分钟的Mn涂膜。通过光学显微镜检查涂层合金的微观结构,组成和相结构。 ,场发射扫描电子显微镜,X射线衍射和能量色散X射线光谱。 Ti-29Nb合金的显微组织在针状结构中显示α相,而Ti-29Nb-15Hf合金在等轴结构中显示β相。随着溅射时间的增加,Ti-29Nb合金上的Mn涂层的圆形颗粒在内表面和外表面均增加。随着溅射时间的增加,Ti-29Nb-xHf合金中等离子电解氧化膜的[Mn + Ca / P]比增加。 Ti-29Nb合金上的Mn涂层的腐蚀电位(Ecorr)比Ti-29Nb-15Hf合金上的Mn涂层的腐蚀电位(Ecorr)高。 Ti-29Nb合金上的Mn涂层和Ti-29Nb-15Hf合金上的Mn涂层的无源电流密度(I-pass)比非Mn涂层的Ti-29Nb和Ti-29Nb-15Hf合金表面的惰性电流密度低。 (C)2017 Elsevier B.V.保留所有权利。

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