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Titanium plate supported MoS2 nanosheet arrays for supercapacitor application

机译:钛板支持的MoS2纳米片阵列用于超级电容器

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摘要

A promising new concept is to apply binder-free supercapacitor electrode by directly growing active materials on current collectors. However, there are many challenges to be solved, such as fabrication of well quality electronic contact and good mechanical stability films through a simple and feasible method. In this study, MoS2 nanosheet arrays supported on titanium plate has been synthesized by a hydrothermal method without other additives, surface active agents and toxic reagents. As the supercapacitor electrode, a good capacitance of 133 Fg(-1) is attained at a discharge current density of 1 A g(-1). The specific energy density is 11.11 Wh kg(-1) at a power density of 0.53 kW kg(-1). Moreover, the electrode shows an excellent cyclic stability. The loss of capacity is only 7% even after 1000 cycles. In addition, the formation mechanism is proposed. The facile method of fabricating MoS2 nanosheet arrays on titanium plate affords an green and effective way to prepare other metal sulfides for the application in electrochemical capacitors. (C) 2016 Elsevier B.V. All rights reserved.
机译:一个有前途的新概念是通过在集电器上直接生长活性材料来应用无粘合剂的超级电容器电极。然而,有许多挑战需要解决,例如通过简单可行的方法来制造高质量的电子触点和良好的机械稳定性薄膜。在这项研究中,通过水热法合成了载于钛板上的MoS2纳米片阵列,而没有其他添加剂,表面活性剂和有毒试剂。作为超级电容器电极,在1 A g(-1)的放电电流密度下可获得133 Fg(-1)的良好电容。在0.53 kW kg(-1)的功率密度下,比能量密度为11.11 Wh kg(-1)。此外,电极显示出优异的循环稳定性。即使经过1000次循环,容量损失也仅为7%。另外,提出了形成机理。在钛板上制造MoS2纳米片阵列的简便方法为制备用于电化学电容器的其他金属硫化物提供了一种绿色有效的方法。 (C)2016 Elsevier B.V.保留所有权利。

著录项

  • 来源
    《Applied Surface Science》 |2017年第2期|1466-1471|共6页
  • 作者单位

    Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China|Chinese Acad Sci, Natl Engn Res Ctr Fine Petrochem Intermediates, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China|Univ Chinese Acad Sci, Beijing 100049, Peoples R China;

    Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China|Chinese Acad Sci, Natl Engn Res Ctr Fine Petrochem Intermediates, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China|Univ Chinese Acad Sci, Beijing 100049, Peoples R China;

    Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China|Chinese Acad Sci, Natl Engn Res Ctr Fine Petrochem Intermediates, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China;

    Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China|Chinese Acad Sci, Natl Engn Res Ctr Fine Petrochem Intermediates, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    MoS2 nanosheet arrays; Nanostructure; Hydrothermal method; Supercapacitor;

    机译:MoS2纳米片阵列纳米结构水热法超级电容器;

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