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首页> 外文期刊>Applied Surface Science >Template assisted synthesis of photocatalytic titanium dioxide nanotubes by hot filament chemical vapor deposition method
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Template assisted synthesis of photocatalytic titanium dioxide nanotubes by hot filament chemical vapor deposition method

机译:热丝化学气相沉积法模板辅助合成光催化二氧化钛纳米管

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摘要

Titanium dioxide thin films were deposited conformally over electrospun polymethyl methacrylate (PMMA) fibers by hot filament chemical vapor deposition method. Deposition rates were observed to be very high to allow for rapid coatings. Thermal annealing of as deposited materials leads the clean decomposition of the polymeric inner layer and formation of randomly distributed anatase TiO_2 nanotubes. Nanotubular TiO_2 structure was clearly identified by SEM and that structure is ideal for good photocatalytic activity because of its high surface area per unit volume ratio. FTIR and XPS results show the formation of stoichiometric TiO_2, and the crystalline form of the final nanotubes was found to be anatase (101) after XRD analysis. High photocatalytic activity of TiO_2 nanotubes under UV irradiation was observed with an apparent rate constant of 0.74 h~(-1) for methyl orange decomposition.
机译:通过热丝化学气相沉积法将二氧化钛薄膜保形沉积在电纺聚甲基丙烯酸甲酯(PMMA)纤维上。观察到沉积速率非常高,可以快速涂覆。沉积材料的热退火导致聚合物内层的干净分解,并形成无规分布的锐钛矿型TiO_2纳米管。纳米管TiO_2的结构可以通过SEM清楚地确定,并且该结构由于具有很高的每单位体积比表面积而非常适合具有良好的光催化活性。 FTIR和XPS结果显示化学计量的TiO_2的形成,XRD分析后发现最终纳米管的晶型为锐钛矿(101)。观察到TiO_2纳米管在紫外光下具有较高的光催化活性,其表观速率常数为0.74h〜(-1)。

著录项

  • 来源
    《Applied Surface Science》 |2013年第15期|993-998|共6页
  • 作者单位

    Advanced Technology Research and Application Center, Selcuk University, Turkey,Department of Chemical Engineering, Selcuk University, 42031 Konya, Turkey;

    Department of Chemical Engineering, Selcuk University, Turkey,Advanced Technology Research and Application Center, Selcuk University, Turkey;

    Department of Chemical Engineering, Selcuk University, Turkey;

    Department of Chemistry, Karamanoglu Mehmet Bey University, Turkey;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Chemical vapor deposition; Titanium dioxide; Photocatalysis;

    机译:化学气相沉积;二氧化钛;光催化;

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