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Surface treatment of aramid fiber by air dielectric barrier discharge plasma at atmospheric pressure

机译:大气压下空气介电阻挡放电等离子体对芳纶纤维的表面处理

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摘要

Aramid fiber samples are treated by air dielectric barrier discharge (DBD) plasma at atmospheric pressure; the plasma treatment time is investigated as the major parameter. The effects of this treatment on the fiber surface physical and chemical properties are studied by using surface characterization techniques. Scanning electron microscopy (SEM) is performed to determine the surface morphology changes, X-ray photoelectron spectroscopy (XPS) is analyzed to reveal the surface chemical composition variations and dynamic contact angle analysis (DCAA) is used to examine the changes of the fiber surface wettability. In addition, the wetting behavior of a kind of thermoplastic resin, poly(phthalazinone ether sulfone ketone) (PPESK), on aramid fiber surface is also observed by SEM photos. The study shows that there seems to be an optimum treatment condition for surface modification of aramid fiber by the air DBD plasma. In this paper, after the 12 s, 27.6 W/cm3 plasma treatment the aramid fiber surface roughness is significantly improved, some new oxygen-containing groups such as C-0, C=0 and 0=C-0 are generated on the fiber surface and the fiber surface wettability is greatly enhanced, which results in the better wetting behavior of PPESK resin on the plasma-treated aramid fiber.
机译:芳族聚酰胺纤维样品在大气压力下通过空气电介质阻挡放电(DBD)等离子体处理;以等离子处理时间为主要参数。通过使用表面表征技术研究了这种处理对纤维表面物理和化学性质的影响。进行扫描电子显微镜(SEM)以确定表面形态变化,分析X射线光电子能谱(XPS)揭示表面化学成分变化,并使用动态接触角分析(DCAA)来检查纤维表面的变化润湿性。另外,通过SEM照片还观察到一种热塑性树脂,聚(酞嗪酮醚砜酮,PPESK)在芳族聚酰胺纤维表面上的润湿行为。研究表明,空气DBD等离子体对芳纶纤维的表面改性似乎有一个最佳的处理条件。本文在12 s,27.6 W / cm3等离子处理后,芳纶纤维的表面粗糙度得到了显着改善,在纤维上产生了一些新的含氧基团,如C-0,C = 0和0 = C-0表面和纤维表面的可湿性大大提高,这使得PPESK树脂在经等离子体处理的芳纶纤维上具有更好的润湿性能。

著录项

  • 来源
    《Applied Surface Science》 |2011年第9期|p.4165-4170|共6页
  • 作者单位

    Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education) & Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024, China;

    Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education) & Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024, China Liaoning Key Laboratory of Advanced Polymer Matrix Composites Manufacturing Technology, Shenyang Aerospace University, Shenyang 110034, China;

    Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education) & Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024, China Dalian University of Education, Dalian 116021, China;

    Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education) & Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024, China;

    Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education) & Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024, China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Aramid fiber,Air DBD plasma,Treatment time,Surface characterization,Wetting behavior;

    机译:芳纶纤维;空气DBD等离子体;处理时间;表面表征;润湿行为;

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