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Structural and dielectric properties of Ru-based gate/Hf-doped Ta_2O_5 stacks

机译:钌基栅/掺f的Ta_2O_5叠层的结构和介电性能

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摘要

Hf-doped Ta2_O_5 thin films are studied with respect to their composition, dielectric and electrical properties. The incorporation of Hf is performed by sputtering of a 0.7 nm thick Hf layer on top of Ta_2O_5 and subsequent annealing to stimulate diffusion of Hf into Ta_2O_5 and their intermixing. The elemental in-depth distribution of the films is investigated by the time of flight secondary ion mass spectroscopy (ToF-SIMS), which has revealed that Hf and Ta_2O_5 are intermixed throughout the whole thickness. Two sub-layers exist in all the samples - an upper homogeneous Hf-doped Ta_2O_5 sub-layer and a near interfa-cial region which is a mixture of Ta- and Si-oxides. The X-ray reflectivity (XRR) analysis shows existence of interfacial layer with a thickness of about 1.9-2 nm, irrespectively of the total thickness of the stacks. Metal-oxide-Si structures with Ru and RuO_2 metal electrodes have been prepared and investigated in terms of dielectric constant, effective work function (EWF) and interfacial layer parameters. The influence of post-metallization annealing steps on these parameters was also studied.
机译:研究了掺f的Ta2_O_5薄膜的组成,介电性能和电性能。 Hf的掺入是通过在Ta_2O_5顶部溅射0.7 nm厚的Hf层并随后进行退火以刺激Hf扩散到Ta_2O_5中并进行混合来进行的。通过飞行时间二次离子质谱(ToF-SIMS)对薄膜的元素深度分布进行了研究,结果表明Hf和Ta_2O_5在整个厚度范围内相互混合。在所有样品中都存在两个子层-上部均匀的Hf掺杂的Ta_2O_5子层和一个接近的界面区域,该区域是Ta和Si氧化物的混合物。 X射线反射率(XRR)分析表明存在界面层,该界面层的厚度为约1.9-2nm,而与堆叠的总厚度无关。制备了具有Ru和RuO_2金属电极的金属氧化物Si结构,并根据介电常数,有效功函数(EWF)和界面层参数进行了研究。还研究了后金属化退火步骤对这些参数的影响。

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  • 来源
    《Applied Surface Science》 |2011年第17期|p.7876-7880|共5页
  • 作者单位

    Institute of Solid State Physics, Bulgarian Academy of Sciences, 72 Tzarigradsko Chaussee, 1784 Sofia, Bulgaria;

    Institute of Electrical Engineering, Slovak Academy of Sciences, Dubravska cesta 9, 84104 Bratislava, Slovakia,H.H. Wills Physics Laboratory, University of Bristol, Bristol BS8 ITL, UK;

    Institute of Electrical Engineering, Slovak Academy of Sciences, Dubravska cesta 9, 84104 Bratislava, Slovakia;

    Institute of Electrical Engineering, Slovak Academy of Sciences, Dubravska cesta 9, 84104 Bratislava, Slovakia;

    Institute of Solid State Physics, Bulgarian Academy of Sciences, 72 Tzarigradsko Chaussee, 1784 Sofia, Bulgaria;

    Institute of Electrical Engineering, Slovak Academy of Sciences, Dubravska cesta 9, 84104 Bratislava, Slovakia;

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  • 原文格式 PDF
  • 正文语种 eng
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  • 关键词

    hf-doped ta_2o_5 high-k dielectrics; ru-based metal gate; high-k/metal gate stacks;

    机译:掺杂hf的ta_2o_5高k电介质;钌基金属门高k /金属栅叠层;

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