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Effects Of Rf Power On Surface-morphological, Structural And Electrical Properties Of Aluminium-doped Zinc Oxide Films By Magnetron Sputtering

机译:射频功率对磁控溅射铝掺杂氧化锌薄膜表面形貌,结构和电性能的影响

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摘要

Aluminium-doped zinc oxide (ZnO:Al) films were prepared by magnetron sputtering at different radio-frequency powers (P_(rf)) of 50, 100, 150 and 200 W. The properties of the films were characterised by X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), Raman microscopy, and spectrophotometry with the emphasis on the evolution of compositional, surface-morphological, optical, electrical and microstructural properties. XPS spectra showed that within the detection limit the films are chemically identical to near-stoichiometric ZnO. AFM revealed that root-mean-square roughness of the films has almost linear increase with increasing P_(rf). Optical band gap E_(gopt) of the films increases from 3.31 to 3.51 eV when P_(rf) increases from 50 to 200 W. A widening E_(gopt) of the ZnO: Al films compared to the band gap (~3.29 eV)of undoped ZnO films is attributed to a net result of the competition between the Burstein-Moss effect and many-body effects. An electron concentration in the films was calculated in the range of 3.73 × 10~(19) to 2.12 × 10~(20) cm~(-3). Raman spectroscopy analysis indicated that well-identified peaks appear at around 439 cm~(-1) for all samples, corresponding to the band characteristics of the wurtzite phase. Raman peaks in the range 573-579 cm~(-1) are also observed, corresponding to the A_1 (LO) mode of ZnO.
机译:通过磁控溅射以50、100、150和200 W的不同射频功率(P_(rf))制备铝掺杂的氧化锌(ZnO:Al)薄膜。通过X射线光电子表征薄膜的性能光谱学(XPS),原子力显微镜(AFM),拉曼显微镜和分光光度法,重点是成分,表面形态,光学,电学和微观结构性质的演变。 XPS光谱表明,在检出限内,该膜与接近化学计量的ZnO在化学上相同。原子力显微镜显示,薄膜的均方根粗糙度随着P_(rf)的增加几乎呈线性增加。当P_(rf)从50 W增加到200 W时,薄膜的光学带隙E_(gopt)从3.31 eV增加到3.51 eV。ZnO:Al薄膜的E_(gopt)与带隙(〜3.29 eV)相比变宽未掺杂的ZnO薄膜的大量归因于Burstein-Moss效应和多体效应之间竞争的净结果。计算出膜中的电子浓度为3.73×10〜(19)至2.12×10〜(20)cm〜(-3)。拉曼光谱分析表明,所有样品均在439 cm〜(-1)附近出现峰,这与纤锌矿相的能带特征相对应。还观察到拉曼峰在573-579 cm〜(-1)范围内,与ZnO的A_1(LO)模式相对应。

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