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Heterogeneous carbon/N-doped reduced graphene oxide wrapping LiMn_(0.8)Fe_(0.2)PO_4 composite for higher performance of lithium ion batteries

机译:碳/氮掺杂异质还原氧化石墨烯包裹LiMn_(0.8)Fe_(0.2)PO_4复合材料可提高锂离子电池的性能

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摘要

In this work, heterogeneous carbon/N-doped reduced graphene oxide wrapping LiMn0.8Fe0.2PO4 (LMFP/C/N-rGO) composites were synthesized successfully via a simple solvothermal method coupled with further calcination. The composites were characterized by XRD, SEM, TEM and XPS, and their electrochemical properties were evaluated by CV, EIS and charge-discharge test. The LiMn0.8Fe0.2PO4/C particles were uniformly grown on the surface of three-dimensional N-doped reduced graphene oxide (N-rGO). The interconnected N-rGO among LMFP particles and amorphous carbon coating on LMFP surface build a continuous conducive network which helps the fast transmission of electron. Lithium ion batteries with LMFP/C/N-rGO exhibit superior discharge capacity, rate capability and cycling stability, bringing a broad prospect for the future applications.
机译:在这项工作中,通过简单的溶剂热方法和进一步的煅烧成功地合成了碳/氮掺杂的还原异质碳包裹的LiMn0.8Fe0.2PO4(LMFP / C / N-rGO)复合材料。通过XRD,SEM,TEM和XPS对复合材料进行了表征,并通过CV,EIS和充放电测试对其电化学性能进行了评价。 LiMn0.8Fe0.2PO4 / C颗粒均匀地生长在三维N掺杂还原氧化石墨烯(N-rGO)的表面上。 LMFP颗粒之间的相互连接的N-rGO和LMFP表面上的无定形碳涂层构成了一个连续的导电网络,有助于电子的快速传输。具有LMFP / C / N-rGO的锂离子电池展现出卓越的放电容量,倍率能力和循环稳定性,为未来的应用带来广阔的前景。

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