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Characterization of bio-oils and bio-char obtained from the pyrolysis of a mixture of Lolium perenne, Festuca ovina, Festuca rubra and Poa pratensis grasses

机译:热解黑麦草,羊茅,羊茅和草地早熟禾混合物的生物油和生物炭的特性

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摘要

In this work, the yield and chemical characterization of products obtained from the pyrolysis of a mixture of Lolium perenne, Festuca ovina, Festuca rubra and Poa pratensis grasses under an inert atmosphere at 600℃ with a heating rate of 50℃/min was studied. Distribution of the products of pyrolysis grass sample was: moisture: 8 ± 2%, total volatiles: 78 ± 7%, char: 14 ± 5%. Bio-oils were acidic and dark brown liquids and they were separated into oils, asphaltenes and asphaltols by solvent extraction procedures prior to gas chromatography-mass spectrometry (GC-MS) analyses. GC-MS results showed that the bio-oils contained complex mixtures of organic compounds, including acetic acid and a large variety of oxygenated and nitrogenated compounds such as phenols, pyridines, pyrazoles, imidazoles, amines, and ketones. SEM micrographs of the bio-chars indicated amorphous, porous and heterogeneous structure of the bio-char obtained from the grass sample. EDX analysis of the bio-char revealed that bio-char contained K, Ca, P and Mg elements.
机译:在这项工作中,研究了黑麦草,白茅草,小白菜和印度大杂草的混合物在惰性气氛下在600℃和50℃/ min的加热速率下的热解产物的产率和化学性质。热解草样品的产品分布为:水分:8±2%,总挥发物:78±7%,炭:14±5%。生物油是酸性和深棕色液体,在进行气相色谱-质谱(GC-MS)分析之前,通过溶剂萃取程序将其分离为油,沥青质和沥青质。 GC-MS结果表明,生物油中含有多种有机化合物的复杂混合物,其中包括乙酸,以及各种含氧化合物和含氮化合物,例如苯酚,吡啶,吡唑,咪唑,胺和酮。生物炭的SEM显微照片表明,从草样品中获得的生物炭具有非晶,多孔和异质结构。 EDX对生物炭的分析表明,生物炭含有K,Ca,P和Mg元素。

著录项

  • 来源
    《Biofuels》 |2016年第2期|181-189|共9页
  • 作者

    Mustafa Baysal; Yuda Yueruem;

  • 作者单位

    Faculty of Engineering and Natural Sciences, Sabanci University, 34956 Tuzla, Istanbul, Turkey;

    Faculty of Engineering and Natural Sciences, Sabanci University, 34956 Tuzla, Istanbul, Turkey;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Bio-mass; bio-oils; bio-chars; GC-MS analysis; SEM;

    机译:生物质生物油生物炭GC-MS分析;扫描电镜;

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