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Simultaneous acetone-butanol-ethanol fermentation, gas stripping, and full-cell-catalyzed esterification for effective production of butyl oleate

机译:丙酮-丁醇-乙醇同时发酵,气提和全细胞催化酯化反应可有效生产油酸丁酯

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摘要

In this study, aiming to improve the economic feasibility of acetone-butanol-ethanol (ABE) fermentation process, generate valuable products and extend the product chain, esterification catalyzed by Candida sp. 99-125 cells was hybrid with the ABE fermentation-gas-stripping integration system. The gas-stripping condensate that contained concentrated ABE products was directly used for esterification without the participation of toxic organic solvents. Full-cell catalysis temperature and the cell dosage rate on oleate production were evaluated and optimized in the esterification process. Under the optimized conditions (35 degrees C, 8% of cells), similar to 68% of butyl oleate and similar to 12% of ethyl oleate were obtained after 4 h of esterification. The Candida sp. 99-125 cells were able to be reused for at least four cycles. The novel cascade process showed environmental benefits, which also showed promising in improving the economic feasibility of the conventional ABE fermentation process.
机译:本研究旨在提高丙酮丁醇乙醇发酵工艺的经济可行性,生产有价值的产品并扩展产品链,并利用假丝酵母催化酯化反应。 99-125个细胞与ABE发酵气提一体化系统杂交。含有浓缩的ABE产物的汽提冷凝物可直接用于酯化反应,而无需使用有毒的有机溶剂。在酯化过程中评估并优化了全细胞催化温度和细胞剂量对油酸酯产量的影响。在最佳条件下(35摄氏度,8%的细胞),酯化4小时后获得了约68%的油酸丁酯和约12%的油酸乙酯。念珠菌99-125个电池至少可以重复使用四个周期。新的级联工艺显示出环境效益,这也显示出改善常规ABE发酵工艺的经济可行性的前景。

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  • 来源
    《Bioprocess and Biosystems Engineering》 |2018年第9期|1329-1336|共8页
  • 作者单位

    Beijing Univ Chem Technol, Natl Energy R&D Ctr Biorefinery, 15 East Rd North 3rd Ring, Beijing 100029, Peoples R China;

    Beijing Univ Chem Technol, Natl Energy R&D Ctr Biorefinery, 15 East Rd North 3rd Ring, Beijing 100029, Peoples R China;

    Beijing Univ Chem Technol, Coll Chem Engn, Beijing 100029, Peoples R China;

    Beijing Univ Chem Technol, Natl Energy R&D Ctr Biorefinery, 15 East Rd North 3rd Ring, Beijing 100029, Peoples R China;

    Beijing Univ Chem Technol, Natl Energy R&D Ctr Biorefinery, 15 East Rd North 3rd Ring, Beijing 100029, Peoples R China;

    Beijing Univ Chem Technol, Natl Energy R&D Ctr Biorefinery, 15 East Rd North 3rd Ring, Beijing 100029, Peoples R China;

    Beijing Univ Chem Technol, Natl Energy R&D Ctr Biorefinery, 15 East Rd North 3rd Ring, Beijing 100029, Peoples R China;

    Shandong Jiqing Chem Co Ltd, Qingzhou 262500, Shandong, Peoples R China;

    Beijing Univ Chem Technol, Natl Energy R&D Ctr Biorefinery, 15 East Rd North 3rd Ring, Beijing 100029, Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Acetone-butanol-ethanol fermentation; Gas stripping; Esterification; Butyl oleate; Full-cell catalysis;

    机译:丙酮-丁醇-乙醇发酵;气提;酯化;油酸丁酯;全细胞催化;

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