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首页> 外文期刊>British Corrosion Journal >Effect of some phenols on corrosion of Al, Cu, and Al–Cu alloys in NaOH solutions
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Effect of some phenols on corrosion of Al, Cu, and Al–Cu alloys in NaOH solutions

机译:某些酚对NaOH溶液中Al,Cu和Al-Cu合金腐蚀的影响

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摘要

The effect of some phenols (phenol, resorcinol, and pyrogallol) on the corrosion of Al, Cu, and Al–Cu alloys in NaOH solutions was examined with potential–time, polarisation, and weight loss measurements. The additives had only a very slight effect on the passivation of such metals and alloys in 10-5M NaOH, but a significant effect in 0·1M NaOH. The addition of phenol, resorcinol, and pyrogallol decreased the extent of the corrosion of Al, Cu, and Al–Cu alloys, apart from Cu in pyrogallol, the inhibition efficiency in general increasing with increase in the concentrations of the additives. With lower concentrations of resorcinol and pyrogallol, an increase in the corrosion rate of Al and Al–Cu alloys was recorded. The inhibitors affected both the anodic and cathodic reactions, with a greater effect on the anodic reactions. The inhibition was explained on the basis of adsorption of phenols on the electrode surface.
机译:通过电位-时间,极化和失重测量,检查了某些酚(苯酚,间苯二酚和邻苯三酚)对NaOH溶液中Al,Cu和Al-Cu合金的腐蚀的影响。添加剂对这种金属和合金在10 -5 NaOH中的钝化只有很小的影响,而在0·1M NaOH中却有显着影响。除了邻苯三酚中的铜,苯酚,间苯二酚和邻苯三酚的添加降低了Al,Cu和Al-Cu合金的腐蚀程度,其抑制效率通常随添加剂浓度的增加而增加。随着间苯二酚和邻苯三酚的浓度降低,记录到的Al和Al-Cu合金的腐蚀速率增加。抑制剂影响阳极和阴极反应,对阳极反应有更大的影响。基于酚在电极表面上的吸附来解释抑制。

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  • 来源
    《British Corrosion Journal》 |1999年第2期|145-150|共6页
  • 作者单位

    The Electrochemistry and Corrosion Laboratory, National Research Centre, Dokki, Cairo, Egypt;

    The Electrochemistry and Corrosion Laboratory, National Research Centre, Dokki, Cairo, Egypt;

    The Electrochemistry and Corrosion Laboratory, National Research Centre, Dokki, Cairo, Egypt;

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