Direction of unusual mixed-ligand metal-organic frameworks:a new type of 3-D polythreading involving 1-D and 2-D structural motifs and a 2-fold interpenetrating porous network

Miao Du; Xiu-Juan Jiang; Xiao-Jun Zhao

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Direction of unusual mixed-ligand metal-organic frameworks:a new type of 3-D polythreading involving 1-D and 2-D structural motifs and a 2-fold interpenetrating porous network

机译：不寻常的混合配体金属有机骨架的发展方向：一种涉及一维和二维结构基序和一种2倍互穿多孔网络的新型3D多线程

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The reaction of Cu~(II) or Cd~(II) acetate with mixed ligands terephthalic (tp) and 3,5-bis(4-pyridyl)-4-amino-1,2,4-triazole (bpt) under the same conditions affords two unusual metal-organic frameworks,in which 1 represents a new type of polythreaded supramolecular architecture consisting of distinct 1-D and 2-D coordination polymers within one crystal,however,2 has an interpenetrating porous network with two similar laterally interlocking 2-D (4,4) layers.

机译：Cu〜（II）或Cd〜（II）乙酸盐与混合配体对苯二甲酸（tp）和3,5-双（4-吡啶基）-4-氨基-1,2,4-三唑（bpt）的反应相同的条件提供了两个不同寻常的金属有机骨架，其中1代表一种新型多线程超分子体系，由一个晶体内的不同的1-D和2-D配位聚合物组成，但2具有互穿的多孔网络和两个相似的横向互锁2-D（4,4）层。

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来源
《Chemical Communications》 |2005年第44期|p.5521-5523|共3页
作者
Miao Du; Xiu-Juan Jiang; Xiao-Jun Zhao;
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College of Chemistry and Life Science,Tianjin Normal University,Tianjin,300074,P.R.China;

College of Chemistry and Life Science,Tianjin Normal University,Tianjin,300074,P.R.China;

College of Chemistry and Life Science,Tianjin Normal University,Tianjin,300074,P.R.China;

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中图分类化学;
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机译：基于双（吡啶基）的配体驱动Ni-II纠缠的金属-有机骨架：从新的1-D + 2-D-> 3-D多线程图案到罕见的3倍互穿ths网络
2. Bis(pyridyl)-based ligands driven Ni-II entangled metal-organic frameworks: From a new 1-D+2-D -> 3-D polythreading motifs to a rare 3-fold interpenetrating ths network [J] . Han Min-Le, Zhao Ying, Li Dong-Sheng, Inorganic Chemistry Communications . 2015,第Null期

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机译：三种新型CD（II）金属有机框架由二吡啶的混合配体构成3,2-D：2,3-F喹喔啉和苯二羧酸酯：来自1-D色带，2-D分层网络，到a三维建筑

Direction of unusual mixed-ligand metal-organic frameworks:a new type of 3-D polythreading involving 1-D and 2-D structural motifs and a 2-fold interpenetrating porous network

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