'Molded' macroporous poly (glycidyl methacrylate-co-trimethylolpropane trimethacrylate materials with fine controlled porous properties: preparation of monoliths using photoinitiated polymerization

Camilla Viklund; Einar Ponten; Borje Glad

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'Molded' macroporous poly (glycidyl methacrylate-co-trimethylolpropane trimethacrylate materials with fine controlled porous properties: preparation of monoliths using photoinitiated polymerization

机译：具有良好控制的多孔性能的“模制”大孔聚甲基丙烯酸缩水甘油酯-三羟甲基丙烷三甲基丙烯酸丙酯材料：使用光引发聚合制备整料

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A model system has been developed for in situ photopolymerization of glycidyl methacrylate and trimethylolpropane trimethacrylate, leading to macroporous monolithic sorbents. This model system allows the preparation of continuous porous objects intended for applications such as detection, separation, and catalysis. The ease of the preparation, the short time needed for reaction, and the possibility of running the reaction at a low temperature are some of the main advantages of the photoinitiated in situ polymerization compared to a thermally initiated polymerization.

机译：已经开发了用于甲基丙烯酸缩水甘油酯和三羟甲基丙烷三甲基丙烯酸酯的原位光聚合的模型系统，从而产生大孔整体式吸附剂。该模型系统允许制备连续的多孔物体，用于检测，分离和催化等应用。与热引发的聚合反应相比，光引发的原位聚合反应的主要优点是易于制备，反应所需的时间短以及在低温下进行反应的可能性。

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《Chemistry of Materials》 |1997年第2期|p.463-471|共9页
作者
Camilla Viklund; Einar Ponten; Borje Glad;
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正文语种 eng
中图分类化学;
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2. Molded rigid polymer monoliths as separation media for capillary electrochromatography. 1. Fine control of porous properties and surface chemistry [J] . Peters EC., Svec F., Frechet JMJ., Analytical chemistry . 1998,第11期

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'Molded' macroporous poly (glycidyl methacrylate-co-trimethylolpropane trimethacrylate materials with fine controlled porous properties: preparation of monoliths using photoinitiated polymerization

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