Kinetic studies on oxygen binding to dicobalt(II) diporphyrin

ZHOU Xiaohai; ZHANG Shaohui; ZHU Dehong; HUANG Suqiu; QU Songsheng

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Kinetic studies on oxygen binding to dicobalt(II) diporphyrin

机译：氧与敌百特（II）双卟啉结合的动力学研究

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It has been an important project in the field of biochemistry to search for a series of synthetic compounds which have good abilities of carrying oxygen at room temperature and simulating the hemoglobin's function of cooperative binding to oxygen. Uemori et al. and Tabushi et al. have reported that some dicobalt(II) diporphyrins have the cooperative effect of binding oxygen in organic solution below 0°C, the Hill coefficients are about 1.0--1.5. We have reported the thermodynamics of a dicobalt(II)diporphyrin binding to oxygen in N,N-dimethylformamide (DMF) at room temperature. It is the first time to report in this note the kinetics of reversible oxygen binding at room temperature by dicobalt(II) diporphyrin.

机译：寻找一系列具有良好的室温携氧能力并模拟血红蛋白与氧气协同结合功能的合成化合物已成为生物化学领域的重要项目。上森等。和Tabushi等。已有报道称，某些双二甲双（二）卟啉具有在0°C以下有机溶液中结合氧的协同作用，希尔系数约为1.0--1.5。我们已经报道了在室温下二邻苯二甲酸二卟啉与N，N-二甲基甲酰胺（DMF）中的氧结合的热力学。这是首次在本报告中报道双草双（二）双卟啉在室温下可逆氧结合的动力学。

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来源
《Chinese science bulletin》 |1996年第6期|p.475-479|共5页
作者
ZHOU Xiaohai; ZHANG Shaohui; ZHU Dehong; HUANG Suqiu; QU Songsheng;
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作者单位

Department of Chemistry, Wuhan University, Wuhan 430072, China;

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原文格式 PDF
正文语种 eng
中图分类自然科学现状及发展;
关键词
dicobalt(II) diporphyrins; model compounds of hemoglobin; kinetics of reversible oxygen binding;

机译：双卟啉（II）双卟啉;血红蛋白模型化合物;可逆氧结合动力学;

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1. Kinetic studies on oxygen binding to dicobalt(II) diporphyrin [J] . ZHOU Xiaohai, ZHANG Shaohui, ZHU Dehong, Chinese science bulletin . 1996,第6期

机译：氧与敌草双（II）双卟啉结合的动力学研究
2. Thermodynamic Study o Dioxygen Binding of Diiron (II) and Dicobalt (II) Complexes containing Various Dinucleating Ligands [J] . Hideki Sugimoto, Toshihiko Nagayama, Sachihito Maruyama, Bulletin of the Chemical Society of Japan . 1998,第10期

机译：含多种双核配体的二价铁与二价钴配合物的热力学研究
3. Reactivity toward Dioxygen of Dicobalt Face-to-Face Diporphyrins in Aprotic Media. Experimental and Theoretical Aspects. Possible Mechanistic Implication in the Reduction of Dioxygen [J] . Yves Le Mest, Claude Inisan, Andre Laouenan Journal of the American Chemical Society . 1997,第26期

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机译：锰（II）-双膦配位化合物的氧结合研究。
6. Magnetic Circular Dichroism Study of a Dicobalt(II) Complex with Mixed 5- and 6-Coordination: A Spectroscopic Model for Dicobalt(II) Hydrolases [O] . James A. Larrabee, W. Rainey Johnson, Adam S. Volwiler -1

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7. Thermodynamic Study on Dioxygen Binding of Diiron(II) and Dicobalt(II) Complexes Containing Various Dinucleating Ligands [O] . Sugimoto, Hideki, Nagayama, Toshihiko, Maruyama, Sachihito, 1998

机译：Thermodynamic study on Dioxygen Binding of Diiron(II) and Dicobalt(II) Complexes Containing Various Dinucleating Ligands
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机译：钼（VI）和钨（VI）与（硫代） - （sulfenato）钴（III）配合物的氧代二过氧配合物的氧转移反应动力学研究

Kinetic studies on oxygen binding to dicobalt(II) diporphyrin

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