Abnormal behavior of fluorescence quenching of gramicidin A in phase transition on lipid veicles by hypocrellin B-Does an electron transfer inverted region exist?

Yue Jiachang; Li Yeping; Su Yaxian

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Abnormal behavior of fluorescence quenching of gramicidin A in phase transition on lipid veicles by hypocrellin B-Does an electron transfer inverted region exist?

机译：降糖素B在脂质囊泡上的相变过程中，短杆菌肽A荧光猝灭的异常行为-是否存在电子转移反向区？

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The fluorescence of gramicidin A(GA)in lipid bilayer may be quenched by Hypocre- llin B. When the phospholipids undergo a phase transition from gel to liquid crystalline phase, the reaction rate decreases unusually. This phenomenon has been analyzed by Marcus' pho- toinduced electron theory, and an electron transfer inverted region hypothesis is proposed, which may adequately explain this abnormal phenomenon.

机译：脂质双分子层中的杆菌肽A（GA）的荧光可被Hycrecrelinin B淬灭。当磷脂经历从凝胶到液晶相的相变时，反应速率会异常降低。已经用马库斯的光致电子理论分析了这种现象，并提出了电子转移倒区假设，可以充分解释这种异常现象。

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《Chinese science bulletin》 |1999年第21期|p.1978-1983|共6页
作者
Yue Jiachang; Li Yeping; Su Yaxian;
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正文语种 eng
中图分类自然科学现状及发展;
关键词
fluorescence quenching; hypocrellin B; Marcus theory;

机译：荧光猝灭;苏必利尔B;马库斯理论;

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专利

1. Synthesis and cation-mediated electron transfer in intramolecular fluorescence quenching of donor-acceptor podands: observation of Marcus inverted region in forward electron transfer reactions [J] . Jiang H., Ye JP., Xu HJ. Journal of the Chemical Society. Perkin Transactions 2 . 2000,第0期

机译：供体-受体配体的分子内荧光猝灭中的合成和阳离子介导的电子转移：正电子转移反应中Marcus反向区域的观察
2. The Inverted Region of Electron Transfer in Intramolecular Fluorescence Quenching of Quinolinium Betaines [J] . G. Kaeb, Th. Engel, H. Lanig, Berichte der Bunsengesellschaft fur Physikalische Chemie . 1995,第2期

机译：喹啉甜菜碱分子内荧光猝灭中电子转移的反向区域
3. Characterizing the behavior and properties of an excited electronic state: electron-transfer mediated quenching of fluorescence [J] . Lars Poulsen, Arantza Zabala Ruiz, Steen Uttrup Pedersen, Journal of Chemical Education . 2003,第7期

机译：表征激发电子态的行为和性质：电子转移介导的荧光猝灭
4. Pressure effects on the structure and phase behavior of phospholipid-gramicidin bilayer membranes [C] . J. Eisenblaetter, M. Zein, R. Winter, International conference on high pressure bioscience and biotechnology . 2002

机译：对磷脂 - 甘霉素双层膜结构和相行为的压力影响
5. Electron transfer through u -shaped donor -bridge -acceptor molecules and fluorescence quenching of conjugated polyelectrolyte [D] . Liu, Min 2005

机译：通过u形供体-桥-受体分子进行电子转移和共轭聚电解质的荧光猝灭
6. Inverted micellar intermediates and the transitions between lamellar cubic and inverted hexagonal lipid phases. I. Mechanism of the L alpha----HII phase transitions. [O] . D P Siegel 1986

机译：胶束中间体倒置以及层状立方和倒六角形脂质相之间的过渡。 I. L alpha ---- HII相变的机制。
7. Inverted micellar intermediates and the transitions between lamellar, cubic, and inverted hexagonal lipid phases. I. Mechanism of the L alpha----HII phase transitions. [O] . Siegel, D P 1986

机译：胶束中间体倒置以及层状，立方和倒六角形脂质相之间的过渡。 I. L alpha ---- HII相变的机制。
8. Fast Interfacial Electron Transfer: Evidence for Inverted Region Kinetic Behavior [R] . Lu, H., Preiskorn, J. N., Hupp, J. T. 1993

机译：快速界面电子转移：反转区域动力学行为的证据

Abnormal behavior of fluorescence quenching of gramicidin A in phase transition on lipid veicles by hypocrellin B-Does an electron transfer inverted region exist?

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