Oxidation of formaldehyde and its interaction with nitric oxide in a flow reactor

P. Glarborg; M.U. Alzueta; K. Kjaergaard; K. Dam-Johansen

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Oxidation of formaldehyde and its interaction with nitric oxide in a flow reactor

机译：流动反应器中甲醛的氧化及其与一氧化氮的相互作用

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The oxidation of formaldehyde in a flow reactor has been studied experimentally under diluted conditions at 800 to 1400 K and with the stoichiometry between fuel-rich and very lean. Of particular interest was the interaction of formaldehyde with nitrogen oxides. The results show that the oxidation of CH_2O is initiated above 900 K, with the oxidation rate decreasing slightly with increasing [O_2]. Addition of NO under fuel-rich conditions inhibits oxidation, while under lean conditions a mutually promoted oxidation of CH_2O and NO is observed at 750―1100 K. Based partly on recent accurate measurements of key reactions of CH_2O and HCO, a detailed reaction mechanism for the oxidation of formaldehyde under post-flame conditions is proposed. It provides a good description of the experimental measurements as well as data from the literature.

机译：在流动反应器中甲醛的氧化已在稀释条件下在800至1400 K的条件下进行了实验研究，其化学计量在富燃料和稀燃料之间。特别令人感兴趣的是甲醛与氮氧化物的相互作用。结果表明，在900 K以上开始CH_2O的氧化反应，氧化速率随[O_2]的增加而降低。在燃料丰富的条件下添加NO可以抑制氧化，而在稀薄条件下在750〜1100 K时可以观察到CH_2O和NO的相互促进的氧化作用。提出了后燃烧条件下甲醛的氧化方法。它为实验测量以及文献数据提供了很好的描述。

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来源
《Combustion and Flame》 |2003年第4期|p.629-638|共10页
作者
P. Glarborg; M.U. Alzueta; K. Kjaergaard; K. Dam-Johansen;
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作者单位

Department of Chemical Engineering, Technical University of Denmark, 2800 Lynghy, Denmark;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类燃料与燃烧;
关键词
formaldehyde oxidation; NO sensitization; chemical kinetics;

机译：甲醛氧化;NO敏化;化学动力学;

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机译：在10 atm的喷射搅拌反应器中一氧化氮与烃氧化的相互作用
2. PYRIDINE CONVERSION IN A FLOW REACTOR AND ITS INTERACTION WITH NITRIC OXIDE [J] . M.U. ALZUETA, A.TENA, R. BILBAO Combustion Science and Technology . 2002,第10期

机译：吡啶在流动反应器中的转化及其与一氧化氮的相互作用
3. Controlled nitric oxide production via O(sup1/supD)? +?Nsub2/subO reactions for use in oxidation flow reactor studies [J] . Lambe Andrew, Massoli Paola, Zhang Xuan, Atmospheric Measurement Techniques . 2017,第6期

机译：通过O（ 1 D）控制一氧化氮的产生？ +？N _{2 O反应用于氧化流反应器研究}
4. KINETIC MODELING OF NON-HYDROCARBON/NITRIC OXIDE INTERACTIONS IN A FLOW REACTOR ABOVE 1400K [C] . Shaozeng SUN, Huali CAO, Zhiqiang WANG, The 7th China-Korea Workshop on Clean Energy Technology（第七届中韩清洁能源技术研讨会） . 2008

机译：1400K以上流动反应器中非烃类/一氧化氮相互作用的动力学模型
5. A study of the interactions of nitric oxide and nitric oxide containing molecules with heme proteins. [D] . Copeland, Daniel Morris. 2006

机译：一氧化氮和含一氧化氮的分子与血红素蛋白相互作用的研究。
6. Interaction of nitric oxide with non-haem iron sites of Escherichia coli bacterioferritin: reduction of nitric oxide to nitrous oxide and oxidation of iron(II) to iron(III). [O] . N E Le Brun, S C Andrews, G R Moore, 1997

机译：一氧化氮与大肠杆菌细菌铁蛋白的非血红素铁位点的相互作用：将一氧化氮还原为一氧化二氮并将铁（II）氧化为铁（III）。
7. Controlled nitric oxide production via O(1D)  + N2O reactions for use in oxidation flow reactor studies [O] . Lambe Andrew, Massoli Paola, Zhang Xuan, 2017

机译：通过O（1D）+ N2O反应控制一氧化氮生产，用于氧化流反应器研究
8. Claremont Atmospheric Free-Radical Study: Measurements of Formaldehyde, HydrogenPeroxide, Nitric Acid, Nitrous Acid, Peroxyacetyl Nitrate, Nitrogen Dioxide, Nitrogen Oxides, Ozone, Carbon Monoxide, Hydrocarbons (C1-C12), and Carbonyl Compounds (C1-Benzald [R] . Mackay, G. I. 1994

机译：Claremont大气自由基研究：甲醛，氢过氧化物，硝酸，亚硝酸，过氧乙酰硝酸盐，二氧化氮，氮氧化物，臭氧，一氧化碳，碳氢化合物（C1-C12）和羰基化合物（C1-Benzald）的测量

Oxidation of formaldehyde and its interaction with nitric oxide in a flow reactor

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