Heats of Formation of HNO and some Related species

William R.Anderson

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Heats of Formation of HNO and some Related species

机译：HNO和一些相关物种的形成热

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A critical review of the heat of formation of HNO is presented. This molecule and its thermodynamics parameters play crucial roles in the chemical mechanisms of propellant combustion and NO_x pollutant chemistry. It was found that predissociation experiments, which have gone largely unoticed for about 15 years, lead to a significant revision in the recommended value.

机译：提出了对HNO形成热的严格审查。该分子及其热力学参数在推进剂燃烧和NO_x污染物化学过程中起着至关重要的作用。发现离解实验在大约15年的时间里基本上没有发生变化，导致对推荐值的重大修改。

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《Combustion and Flame》 |1999年第2期|p.394-403|共10页
作者
William R.Anderson;
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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类燃料与燃烧;
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专利

1. Discriminating formation of HNO from other reactive nitrogen oxide species. [J] . Donzelli S, Espey MG, Thomas DD, Free Radical Biology and Medicine: The Official Journal of the Oxygen Society . 2006,第6期

机译：区分HNO和其他反应性氮氧化物的形成。
2. Investigation of thermally grown oxide on 4H-SiC by a combination of H_2O and HNO_3 vapor with varied HNO_3 solution heating temperature [J] . Banu Poobalan, Jeong Hyun Moon, Sang-Cheol Kim, Applied Surface Science . 2013,第PtaB期

机译：H_2O和HNO_3蒸气在不同HNO_3溶液加热温度下的组合研究4H-SiC上热生长氧化物
3. The heats of interaction of L-glutamine and L-glutamic acid with KOH and HNO3 in aqueous solutions [J] . Gridchin SN, Romodanovskii PA, Pyreu DF Russian Journal of Physical Chemistry . 2009,第1期

机译：L-谷氨酰胺和L-谷氨酸与KOH和HNO3在水溶液中的相互作用热
4. Redox Potential Evolution of nitric species and plutonium in HNO_3-HNO_2 system [C] . N. Larabi-Gruet, E. Buravand, B. Gwinner, ECS Meeting . 2012

机译：HNO_3-HNO_2系统氧化还原潜在演化和钚钚
5. Effects of drought and/or high temperature stress on wild wheat relatives (Aegilops species) and synthetic wheats. [D] . Pradhan, Gautam Prasad. 2011

机译：干旱和/或高温胁迫对野生小麦亲缘种（Aegilops物种）和合成小麦的影响。
6. Hydrogen Sulfide Sensing through Reactive Sulfur Species (RSS) and Nitroxyl (HNO) in Enterococcus faecalis [O] . Jiangchuan Shen, Brenna J. C. Walsh, Ana Lidia Flores-Mireles, -1

机译：粪肠球菌中的反应性硫化物（RSS）和硝基氧（HNO）对硫化氢的检测
7. This article presents a new numerical model describing the behaviour of a thermally thick wood sample exposed to high solar heat flux (above 1 MW/m2). A preliminary study based on dimensionless numbers is used to classify the problem and support model building assumptions. Then, a model based on mass, momentum and energy balance equations is proposed. These equations are coupled with liquid-vapour drying model and pseudo species biomass degradation model. By comparing to a former experimental study, preliminary results have shown that these equations are not enough to accurately predict biomass behaviour under high solar heat flux. Indeed, a char layer acting as radiative shield forms on the sample exposed surface. In addition to this classical set of equations, it is mandatory to take into account radiation penetration into the medium. Furthermore, as biomass contains water, medium deformation consecutively to char steam gasification must also be implemented. Finally, with the addition of these two strategies, the model is able to properly capture the degradation of biomass when exposed to high radiative heat flux over a range of sample initial moisture content. Additional insights of biomass behaviour under high solar heat flux were also derived. Drying, pyrolysis and gasification fronts are present at the same time inside of the sample. The coexistence of these three thermochemical fronts leads to char gasification by the steam produced from drying of the sample, which it is the main phenomenon behind medium ablation. [O] . Pozzobon, Victor, Salvador, Sylvain, Bézian, Jean Jacques 2018

机译：本文提供了一个新的数值模型，该模型描述了暴露于高太阳热通量（高于1 / MW / m2）的热厚木材样品的行为。基于无量纲数的初步研究用于对问题进行分类并支持模型构建假设。然后，提出了一种基于质量，动量和能量平衡方程的模型。这些方程式与液体蒸汽干燥模型和假物种生物质降解模型耦合。通过与以前的实验研究进行比较，初步结果表明，这些方程不足以准确预测高太阳热通量下的生物量行为。的确，在样品暴露的表面上形成了充当辐射屏蔽层的炭层。除了这套经典的方程式之外，还必须考虑到辐射向介质的渗透。此外，由于生物质中含有水，因此还必须在炭蒸气汽化后进行连续的介质变形。最后，通过添加这两种策略，该模型能够在一定范围的样品初始水分含量下暴露于高辐射热通量的情况下，正确捕获生物质的降解。还得出了在高太阳热通量下生物量行为的其他见解。样品内部同时存在干燥，热解和气化前沿。这三个热化学前沿的共存会导致样品干燥产生的蒸汽产生焦炭气化，这是介质烧蚀的主要现象。
8. Critical Review of the Heats of Formation of HNO and Some Related Species [R] . Anderson, W. R. 1997

机译：HNO及其相关物种形成热的批判性回顾

Heats of Formation of HNO and some Related species

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