Recent advances in the chemistry of tris(thiolato) bridged cyclopentadienyl dimolybdenum complexes

Petillon Francois Y.; Schollhammer Philippe; Talarmin Jean

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Recent advances in the chemistry of tris(thiolato) bridged cyclopentadienyl dimolybdenum complexes

机译：三硫代桥连环戊二烯基二钼配合物化学的最新进展

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The chemistry of tris(thiolato) bridged dimolybdenum compounds in low oxidation states (mostly III) is considered. Various synthetic routes lead to chalcogenide-bridged dinuclear complexes of group 6 metals (mainly Mo). Extensive chemistry of these derivatives is reviewed. Their reactivity towards various reagents such as alkynes, isonitriles, nitriles, propargylic alcohols, azides, hydrazines, carbon disulfide ..., demonstrates their ability for activation of small unsaturated molecules through new C-X (X = C, N, O, S...) bonds formation or cleavage. (C) 2016 Elsevier B.V. All rights reserved.

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来源
《Coordination chemistry reviews》 |2017年第1期|73-92|共20页
作者
Petillon Francois Y.; Schollhammer Philippe; Talarmin Jean;
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作者单位

Univ Bretagne Occidentale, CNRS, UMR 6521, Chim Electrochim Mol & Chim Analyt,CS 93837, F-29238 Brest 3, France;

Univ Bretagne Occidentale, CNRS, UMR 6521, Chim Electrochim Mol & Chim Analyt,CS 93837, F-29238 Brest 3, France;

Univ Bretagne Occidentale, CNRS, UMR 6521, Chim Electrochim Mol & Chim Analyt,CS 93837, F-29238 Brest 3, France;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
Molybdenum; S-donor bridging ligands; Cyclopentadienyl ligands; Bond activation;

机译：钼;S-给体桥联配体;环戊二烯基配体;键活化;

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2. Dimolybdenum and ditungsten cyclopentadienyl carbonyls with electron-rich phosphido bridges. Synthesis of the hydrido phosphido complexes [M2Cp2(mu-H)(mu-PRR ')(CO)(4)] and unsaturated bis(phosphido) complexes [M2Cp2(mu-PR2)(mu-PR ' R '')(CO)(x)] (x= [J] . Garcia ME., Riera V., Ruiz MA., Organometallics . 2002,第25期

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Recent advances in the chemistry of tris(thiolato) bridged cyclopentadienyl dimolybdenum complexes

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