Dinitrogen activation by group 4 and group 5 metal complexes supported by phosphine-amido containing ligand manifolds

Burford Richard J.; Yeo Alyssa; Fryzuk Michael D.

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Dinitrogen activation by group 4 and group 5 metal complexes supported by phosphine-amido containing ligand manifolds

机译：含膦酰胺基的配位体支链支持的第4组和第5组金属配合物的二氮活化

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This review surveys the iterative approaches to ligand design for groups 4 and 5 transition metal complexes relevant to nitrogen fixation made by the Fryzuk group over the last 25 years. The coordination chemistry of multidentate ligands that incorporate phosphine and amido donors with zirconium, titanium, tantalum and niobium, and their ability to bind and functionalize molecular nitrogen is surveyed. In this review, the sequential design of these ligand sets is documented with the ultimate, as yet unrealized goal to discover a homogeneous system that can use dinitrogen as a feedstock and convert it to higher value organo-nitrogen materials in a catalytic process. (C) 2016 Elsevier B.V. All rights reserved.

机译：这篇综述调查了过去25年中Fryzuk组进行的与固氮有关的第4组和第5组过渡金属配合物配体设计的迭代方法。研究了将膦和酰胺供体与锆，钛，钽和铌结合在一起的多齿配体的配位化学，以及它们结合和官能化分子氮的能力。在这篇综述中，这些配体对的顺序设计记录了最终的，尚未实现的目标，即发现一个均质系统，该系统可以使用二氮作为原料，并在催化过程中将其转化为更高价值的有机氮材料。（C）2016 Elsevier B.V.保留所有权利。

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来源
《Coordination chemistry reviews》 |2017年第3期|84-99|共16页
作者
Burford Richard J.; Yeo Alyssa; Fryzuk Michael D.;
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作者单位

Univ British Columbia, Dept Chem, 2036 Main Mall, Vancouver, BC V6T 1Z1, Canada;

Univ British Columbia, Dept Chem, 2036 Main Mall, Vancouver, BC V6T 1Z1, Canada;

Univ British Columbia, Dept Chem, 2036 Main Mall, Vancouver, BC V6T 1Z1, Canada;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
Ligand design; Dinitrogen activation; Titanium; Zirconium; Niobium; Tantalum;

机译：配体设计;二氮活化;钛;锆;铌;钽;

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1. Bimetallic Cobalt-Dinitrogen Complexes: Impact of the Supporting Metal on N-2 Activation [J] . Clouston Laura J., Bernales Varinia, Carlson Rebecca K., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2015,第19期

机译：双金属钴-二氮配合物：支撑金属对N-2活化的影响
2. Transition metal dinitrogen complexes supported by a versatile monoanionic [N_2P_2] ligand [J] . Wayne A. Chomitz, John Arnold Chemical Communications . 2007,第45期

机译：多功能单阴离子[N_2P_2]配体支持的过渡金属二氮配合物
3. Hetero-dinuclear complexes of 3d metals with a bridging dinitrogen ligand: theoretical prediction of the characteristic features of geometry and spin multiplicity [J] . Nakagaki Masayuki, Sakaki Shigeyoshi Physical chemistry chemical physics: PCCP . 2016,第38期

机译：具有桥接二氮配体的3d金属异核复合物：几何特征和自旋多重性的理论预测
4. Synthesis and Characterization of Multinuclear Transition Metal Complexes Containing {Cp*M} Fragments (M = Rh, Ir) Supported by Linearly Ordered Tetraphosphine Ligand [C] . Akika Yoshii, Hiroko Nagata, Takayuki Nakajima Symposium on Organometallic Chemistry . 2008

机译：通过线性有序的四膦配体（M = RH，IR）含有（Cp * M}片段（M = RH，IR）的多核过渡金属配合物的合成与表征
5. Ligand design and the synthesis of reactive organometallic complexes of tantalum for dinitrogen activation. [D] . Johnson, Samuel Alan. 2001

机译：钽的配体设计和反应性有机金属配合物的合成，用于二氮活化。
6. Terminal Iron–Dinitrogen and Iron–Imide Complexes Supported by a Tris(phosphino)borane Ligand [O] . Marc-Etienne Moret, Jonas C. Peters -1

机译：TRIS（磷酸氨磷）硼烷配体负载的末端铁 - 二煤层和铁 - 酰亚胺配合物
7. Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand [O] . Moret, Marc-Etienne, Peters, Jonas C. 2011

机译：三（膦）硼烷配体支撑的末端铁二氮和酰亚胺亚铁配合物

Dinitrogen activation by group 4 and group 5 metal complexes supported by phosphine-amido containing ligand manifolds

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