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首页> 外文期刊>Coordination chemistry reviews >Transition-metal-catalyzed transfer carbonylation with HCOOH or HCHO as non-gaseous C1 source
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Transition-metal-catalyzed transfer carbonylation with HCOOH or HCHO as non-gaseous C1 source

机译：以HCOOH或HCHO作为非气态C1源的过渡金属催化转移羰基化

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摘要

While carbon monoxide (CO) gas has been extensively applied in the bulk chemical industry, its intrinsic properties such as high toxicity, flammability, and special equipment requirement for handling, limit its utilization in organic synthesis, fine chemical industry and academia. Recently, considerable effort has been devoted to the development of CO surrogates to avoid the direct use of carbon monoxide gas. Among the various CO surrogates, formic acid and formaldehyde, have a broad range of applications in organic synthesis. The direct carbonylation with formic acid (HCOOH) and formaldehyde (HCHO) represents one of the most atom-economical substitutes owing to their high weight percentage of CO. In this review, the potential roles of both formic acid and formaldehyde in transition-metal catalyzed carbonylation reactions are discussed. In order to understand these transfer carbonylation reactions, the mechanistic rationale for representative examples is also provided. (C) 2017 Elsevier B.V. All rights reserved.
机译：虽然一氧化碳（CO）气体已广泛应用于散装化学工业，但其固有特性（如高毒性，易燃性和特殊的处理设备要求）限制了其在有机合成，精细化工和学术界中的利用。近来，为避免直接使用一氧化碳气体，已经投入了大量的精力来开发CO代用品。在各种CO代用品中，甲酸和甲醛在有机合成中具有广泛的应用。甲酸（HCOOH）和甲醛（HCHO）的直接羰基化由于其CO的重量百分比较高，因此是最经济的原子取代之一。在本文中，甲酸和甲醛在过渡金属催化中的潜在作用讨论了羰基化反应。为了理解这些转移羰基化反应，还提供了代表性实例的机械原理。 （C）2017 Elsevier B.V.保留所有权利。

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  • 来源
    《Coordination chemistry reviews》 |2017年第4期|43-53|共11页
  • 作者

    Cao Jian; Zheng Zhan-Jiang; Xu Zheng; Xu Li-Wen;

  • 作者单位

    Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 311121, Zhejiang, Peoples R China;

    Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 311121, Zhejiang, Peoples R China;

    Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 311121, Zhejiang, Peoples R China;

    Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 311121, Zhejiang, Peoples R China|Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China;

  • 收录信息 美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Carbonylation; Transition-metal catalysis; Non-gaseous C1 source; CO surrogates;

    机译：羰基化;过渡金属催化;非气态C1来源;CO替代物;

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