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STM probing the supramolecular coordination chemistry on solid surface: Structure, dynamic, and reactivity

机译：STM探索固体表面上的超分子配位化学：结构，动力学和反应性

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摘要

Supramolecular coordination chemistry is currently a very popular topic in metallorganic chemistry and has a very large impact on a broad field of applications. More importantly, the invention of STM has opened new doorways to study these concepts on surfaces. This review summarizes the recent progress on surface-confined metallosupramolecular engineering based on the supramolecular coordination chemistry, with the aid of STM. At the beginning, a discussion of metalloids, alkali metals, and alkaline earth metal-based metallosupramolecular engineering is conducted. Next, transition metal-based coordination chemistry on surfaces is discussed. Then, polygonal, double- and triple-decker structures based on rare-earth-metal coordination chemistry are presented. Based on these supramolecular structures, the dynamics of coordination as well as the formed supramolecules are discussed. In the end, the coordination chemistry, including stability of coordination bonds, organic molecules, and gas molecule adsorption is described. Throughout this review, the coordination structures, dynamics and reactivity have been emphasized, which are important current and future research themes. (C) 2017 Elsevier B.V. All rights reserved.
机译：超分子配位化学目前是金属有机化学中非常受欢迎的主题，并且对广泛的应用领域具有很大的影响。更重要的是，STM的发明为研究表面上的这些概念打开了新的大门。这篇综述总结了基于超分子配位化学的表面受限金属超分子工程的最新进展，并借助了STM。在开始时，对准金属，碱金属和基于碱土金属的金属超分子工程进行了讨论。接下来，讨论了基于过渡金属的表面配位化学。然后，提出了基于稀土金属配位化学的多边形，双层和三层结构。基于这些超分子结构，讨论了配位动力学以及形成的超分子。最后，描述了配位化学，包括配位键，有机分子和气体分子吸附的稳定性。在整个审查过程中，强调了协调结构，动力学和反应性，这是当前和未来重要的研究主题。 （C）2017 Elsevier B.V.保留所有权利。

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  • 来源
    《Coordination chemistry reviews》 |2017年第4期|145-177|共33页
  • 作者

    Geng Yan-fang; Li Ping; Li Ji-zhen; Zhang Xue-mei; Zeng Qing-dao; Wang Chen;

  • 作者单位

    Natl Ctr Nanosci & Technol NCNST, CAS Ctr Excellence Nanosci, CAS Key Lab Standardizat & Measurement Nanotechno, 11 Beiyitiao, Beijing 100190, Peoples R China;

    Natl Ctr Nanosci & Technol NCNST, CAS Ctr Excellence Nanosci, CAS Key Lab Standardizat & Measurement Nanotechno, 11 Beiyitiao, Beijing 100190, Peoples R China;

    Tsinghua Univ, Sch Econ & Management, Beijing 100084, Peoples R China;

    Natl Ctr Nanosci & Technol NCNST, CAS Ctr Excellence Nanosci, CAS Key Lab Standardizat & Measurement Nanotechno, 11 Beiyitiao, Beijing 100190, Peoples R China|Tsinghua Univ, Sch Econ & Management, Beijing 100084, Peoples R China;

    Natl Ctr Nanosci & Technol NCNST, CAS Ctr Excellence Nanosci, CAS Key Lab Standardizat & Measurement Nanotechno, 11 Beiyitiao, Beijing 100190, Peoples R China;

    Natl Ctr Nanosci & Technol NCNST, CAS Ctr Excellence Nanosci, CAS Key Lab Standardizat & Measurement Nanotechno, 11 Beiyitiao, Beijing 100190, Peoples R China;

  • 收录信息 美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Coordination chemistry; Supramolecular structures; Dynamic; Activity; Scanning tunneling microscopy;

    机译：配位化学;超分子结构;动力学;活性;扫描隧道显微镜;

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