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Metallomacromolecules containing cobalt sandwich complexes: Synthesis and functional materials properties

机译：含钴夹心复合物的金属大分子：合成与功能材料性能

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摘要

Metallomacromolecules are attracting considerable attention as a class of macromolecular materials with unique properties and applications. Although ferrocene (Fc)-containing macromolecules have occupied the dominant position for several decades in this area and have led to a variety of architectures and applications, the class of cobalt-sandwich-containing macromolecules has recently undergone a booming development. Especially, polymers and dendrimers containing the 18-e cationic cobalticenium (Cc) unit isoelectronic to Fc have been developed during the last few years after overcoming Cc functionalization problems and following the burst of living polymers and dendrimers. Subsequently, remarkable applications have been disclosed including materials physical properties, healthcare and engineering. Meanwhile several other metallopolymers with Co sandwiches containing cyclobutadiene or carborane ligands have also emerged. This review summarizes the most recent progress in the synthesis of metallomacromolecules containing cobalt sandwich complexes and their functional materials properties. Polymerization techniques have included radical polymerization, reversible addition fragmentation chain transfer (RAFT), ring-opening metathesis polymerization (ROMP), condensation polymerization, ring opening polymerization (ROP), and atom transfer radical polymerization (ATRP), and post polymerization has also been used. The applications include the formation of nanostructured materials, magnetic materials, redox recognition and sensing, lithographic patterning, antimicrobial materials, stimuli-responsive materials, catalysis and electrochemical devices. (C) 2017 Elsevier B.V. All rights reserved.
机译：作为一类具有独特性能和应用的高分子材料，金属大分子分子正引起人们的广泛关注。尽管含二茂铁（Fc）的大分子在该领域占据了主导地位数十年，并导致了各种结构和应用，但是含钴三明治的大分子类别最近得到了蓬勃发展。特别是，在克服Cc官能化问题以及活性聚合物和树枝状聚合物爆裂之后的最近几年中，已经开发出含有与Fc等电子的18-e阳离子钴tic（Cc）单元的聚合物和树枝状聚合物。随后，已公开了引人注目的应用，包括材料的物理性能，保健和工程。同时，还出现了几种其他的含Co夹心的金属聚合物，其中含有环丁二烯或碳硼烷配体。这篇综述总结了含钴夹心复合物的金属大分子的合成及其功能材料性能的最新进展。聚合技术包括自由基聚合，可逆加成断裂链转移（RAFT），开环易位聚合（ROMP），缩合聚合，开环聚合（ROP）和原子转移自由基聚合（ATRP），并且后聚合用过的。应用包括纳米结构材料，磁性材料，氧化还原识别和感测，光刻图案形成，抗菌材料，刺激响应材料，催化和电化学装置的形成。 （C）2017 Elsevier B.V.保留所有权利。

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  • 来源
    《Coordination chemistry reviews》 |2017年第4期|34-79|共46页
  • 作者

    Zhao Li; Liu Xiong; Zhang Li; Qiu Guirong; Astruc Didier; Gu Haibin;

  • 作者单位

    Sichuan Univ, Minist Educ, Key Lab Leather Chem & Engn, Chengdu 610065, Peoples R China;

    Sichuan Univ, Minist Educ, Key Lab Leather Chem & Engn, Chengdu 610065, Peoples R China;

    Sichuan Univ, Minist Educ, Key Lab Leather Chem & Engn, Chengdu 610065, Peoples R China;

    Sichuan Univ, Minist Educ, Key Lab Leather Chem & Engn, Chengdu 610065, Peoples R China;

    Univ Bordeaux, ISM, CNRS, UMR 5255, F-33405 Talence, France;

    Sichuan Univ, Minist Educ, Key Lab Leather Chem & Engn, Chengdu 610065, Peoples R China;

  • 收录信息 美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Metallopolymer; Cobalt sandwich; Cobalticenium; Dendrimer; Cyclobutadienecobalt; Cobaltacarborane;

    机译：金属聚合物;钴三明治;钴tic;Dendrimer;环丁二烯钴;钴碳烷;

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